词条 | 陈小明 |
释义 | 1 中科院院士、无机化学家中科院院士、无机化学家。1961年10月5日生于广东省揭阳市。1983年于 中山大学化学系获学士学位,1986年于中山大学化学系获硕士学位,1992年于香港中文大学化学系获博士学位(导师麦松威教授)后回到中山 大学工作。1993年12月晋升副教授,1994年12月破格晋升教授,1996年7月被遴选为无机化学的博士生导师。1999年被教育部聘为长江学者奖励 计划特聘教授。2009年12月当选中国科学院院士。 中文名:陈小明 国籍:中国 民族:汉 出生地:广东省揭阳市 出生日期:1961年10月5日 职业:中科院院士,无机化学家 毕业院校:中山大学,香港中文大学 主要成就:见下方详述 ◎ 履历中国化学会理事,中国稀土学会理事,中国晶体学会理事,《无机化学》、《结构化学》和《中国稀土学报》杂志编委、十多种国际性学术杂志(包括《美国化学会会志》、美国《无机化学》和10种国内学术杂志(包括《中国科学》、《 化学学报》、《中国化学》、《科学通报》、《高校化学学报》等)审稿人,曾担中山大学任化学与化学工程学院院长。 ◎ 科研成果他主要从事功能金属配合物和聚合金属配合物超分子体系的分子设计、合成和结构与性能研究。目前已取得的主要研究成果有三个方面: (1) 1992年起,开展“金属酶活性中心构的小分子模拟”的研究,取得具有特色的进展,合成了多种金属酶活性中心结构的新型模型化 合物并进行深入的结构与催化性质研究。 (2) 1994年起,开展了“具有光电子性能的簇合物与聚合物研究”,创立合成含铜与其它金属的异多核配合物的独特方法,设计和组装新 型异多核金属配合物,在复杂异多核金属配合物的分子设计与合成方面取得新的突破,成功建立起系列铜-稀土18核簇合物及其它铜-稀土异 多核配合物的新颖制备方法,开展复杂金属配合物体系的磁性及光电性质研究,为异金属功能配合物在分子光电器件中的应用研究提供了新的 基础。 (3)成功利用桥连配体与金属离子作为模块组装了大量的、具有不同框架结构的聚合金属配合物,并通过超分子作用等调控聚合物的框架 结构,获得系列具有新颖结构和发光功能等功能的新型有机—金属聚合物,为此类新型无机—有机杂化材料的研制提出新的研究思路和方向。 1993年以来,主持包括国家杰出青年科学基金和国家基金重点项目等10多项国家和省部级科学基金课题。迄今在国内外学术杂志上发表学 术论文230多篇,其中在包括国际第一流的化学杂志《美国化学会会志》、德国《应用化学》、《欧洲化学》等知名学术刊物发表200多篇。部 分论文已被同行在国际性学术杂志上引证1160多次。根据国家科委情报中心的统计,1996年陈小明在国际上发表(《SCI》收录)的论文居全国个人排行榜第五位,1997年国际论文被引用篇数全国个人排位第三名。1999年国际论文被引用篇数全国个人排位第三名。曾应邀在13次国际性 和17次全国性学术会议上作邀请报告。在教学方面,他曾讲授《结构化学》、《波谱化学》、《X射线单晶结构分析》和《金属配合物的现代研究方法》、《现代无机化学》、《 配位化学》等本科生、研究生课程。指导博士后、博士生、硕士生等的科研工作,其中7名博士生和6名硕士生已毕业并获得相应学位。他指导 的一名博士生的学位论文被评为“全国优秀博士论文”(2001年)。 ◎ 获得荣誉由于他在科研和教学等方面取得的成绩,1996年获国家杰出青年科学基金的资助。1997年获第五届“中国青年科技奖”,首届“广东省优 秀青年科学家奖”。1998年,获广东省自然科学奖一等奖(第一完成人)、广东省“十大杰出青年”称号。入选国家“百千万”人才工程97年 度第一、二层次人选。1999年获得求是科学基金会“杰出青年学者奖”。2000年获得中国高等学校科学技术奖二等奖(第三完成人)。2002年 获得中国高等学校科学技术奖二等奖(第一完成人)。 近年作为通讯作者发表的部分论文目录: 2009 1. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, ja-2008-089872. 2. Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold interpenetration: (3,5) connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2009, cg-2008-01308u. 3. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M.,Inorg. Chem. 2009, ic-2008-02446m. 4. A spin-frustrated complex, [FeIIFeIII(trans-1, 4-cyclohexanedicarboxylate)1.5]∞: Interplay between single-chain magnet behavior and magnetic ordering Zheng, Y.-Z.; Xue, W.; Zhang, W.-X.; Tong, M. L.; Chen, X.-M.; Grandjean F.; Long G. J.; Ng, S. W.; Panissod P.; Drillon M.,Inorg. Chem. 2009, 48, 2028–2042. 5. Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue W.; Chen, X.-M.;Dalton Trans 2009, 1396-1406. 6. Syntheses, structures and sorption properties of two framework-isomeric porous copper coordination polymers Xue D.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., CrystEngComm 2009, 11, 183-188. 2008 7. Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Chen, X.-M.; Zheng, S.-L., Inorg. Chem. 2008, 47, 11202–11211. 8. Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.;Chen, X.-M., Cryst. Growth Des. 2008, 8, 4559-4563. 9. Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.;Chen, X.-M.,Cryst. Growth Des. 2008, 8, 3673–3679. 10. (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.;Chen, X.-M., CrystEngComm 2008, 10, 1770-1776. 11. Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.; Chen, X.-M.; Ng, S.W., Chem. Commun. 2008, 4019–4021. 12. Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N., Xue, W., Zhang, W.-X., Chen, X.-M., Chem. Mater. 2008, 20, 5345–5350. 13. Pentanuclear and heptanuclear metal helicates by self-assembly of d metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X., Zhang, J.-P., Lin, Y.-Y.,Chen, X.-M.,Inorg. Chem. 2008, 47, 7389-7395.. 14. Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F., Zhang, Y.-B., Cheng, X.-N., Chen, X.-M., CrystEngComm 2008, 10, 753–758. 15. A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition Zheng, Y.-Z., Xue, W., Tong, M.-L., Zhang, W.-X., Chen, X.-M., Grandjean F.; Long G. J., Inorg. Chem. 2008, 47, 4077-4087. 16. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017. 17. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue W.; Zheng, S.-L.; Tong, M.-L. ; Chen, X.-M.,Adv. Mater. 2008, 20, 1534–1538. 18. Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.;Chen, X.-M.; Wang, H.-Z., Chem. Commun. 2008, 1551-1553. 19. Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2008, 47, 1346-1351. 2007 20. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin canting antiferromagnetic layer Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739. 21. Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology, Hu, S.; Zhang, J.-P.; Tong, M.-L.; Chen, X.-M.; Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289. 22. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China) 23. From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.; Chen, X.-M., Inorg. Chem. 2007, 46, 6437-6443. 24. A tetracarboxylate–bridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 1332-1336. 25. Unprecedented (3,9)-connected (4.6)3(4.6.8) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M., Cryst. Growth Des. 2007, 7, 980–983. 26. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.;Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498. 27. Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170. 28. In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M., Inorg. Chem. 2007, 46, 1135-1143. 2006 29. Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.;Chen, X.-M., Cryst. GrowthDes. 2006, 6, 2739-2746. 30. A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.;Chen, X.-M., Dalton Trans. 2006, 5294-5303. 31. Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.; Chen, X.-M., Gao, S. Inorg. Chem. 2006, 45, 7069-7076. 32. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314. 33. The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]¥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.; Chen, X.-M., Chem. Commun. 2006, 3603-3605. 34. Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M.,Cryst. Growth Des. 2006, 6, 1684-1689. 35. Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate Huang, X.-C.; Li, D.; Chen, X.-M.,CrystEngComm 2006, 8, 351-355. 36. One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1194-1198. 37. (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.;Chen, X.-M., Chem. Commun. 2006, 1689-1699. 38. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559. 39. From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 519–523. 40. Coexistence of spin frustration and long-range magnetic ordering in a triangular Co3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Chem. Commun. 2006, 165–167. 2005 41. Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; andChen, X.-M., Inorg. Chem. 2005, 44, 8285-8292. 42. Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Dalton Trans. 2005, 3681-3685. 43. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M.,J. Am. Chem. Soc. 2005, 127, 14162-14163. 44. Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 1609-1616. 45. Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 4270-4275. 46. A solvothermally in-situ generated mixed-ligand approach for NLO-active metal–organic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.; Chen, X.-M.,Inorg. Chem. 2005, 44, 4148-4149. 47. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets Zeng, M.-H.;Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M.,Angew. Chem. Int. Ed. 2005, 44, 3079-3082. 48. Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M.,Inorg. Chem. 2005, 44, 3146-3150. 49. Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2005, 2232–2234. 50. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506. 51. Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 695–700. 52. Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.; Chen, X.-M.,Cryst. Growth Des. 2005, 5, 617-622. 53. Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M.,Chem. Commun. 2005, 1258–1260. (Hot Paper) 54. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565. 55. Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = Gd or Nd) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.; Chen, X.-M., Inorg. Chem. 2005, 44, 559-565. 56. Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Dalton Trans. 2005, 424-426.(Hot Paper, Highlighted in Chemical Science) 57. Metallophilicity versus p-p interactions: Ligand-unsupported argentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = Cu or Ag, L = tridentate ligand) Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M.,Chem. Eur. J. 2005, 11, 552-561. 2004 58. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219. 59. (Cover Paper) Crystal-to-crystal transformations of a microporous metal-organic laminated framework triggered by guest exchange, dehydration and readsorption Zeng, M.-H.; Feng, X.-L.; Chen, X.-M., Dalton Trans. 2004, 2217-2223. (Highlighted in Chem. Sci.) 60. Syntheses, structures and photoluminescent properties of three silver(I) cluster-based coordination polymer with aromatic heterocycle carboxylates Yang, J.-H.; Zheng, S.-L.; Chen, X.-M., Cryst. Growth Des. 2004, 4, 831-836. 61. Syntheses, structures, and photoluminescence studies of [2:2] metallomacrocyclic silver(I) complexes with 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)benzene Ren, C.-X.; Ye, B.-H.; He, F.; Cheng, L.;Chen, X.-M., CrystEngComm 2004, 6, 200-207. 62. A single-source approach to Bi2S3 and Sb2S3 nanorods via hydrothermal treatmentXie, G.; Qiao, Z.-P.; Zeng, M.-H.; Chen, X.-M.; Gao, S.-L., Cryst. Growth Des. 2004, 4, 513-516. 63. Two new mixed-valence Cu(I,II) imidazolate coordination polymers: Metal-valence tuning approach for new topologic structures Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M.,Chem. Commun. 2004, 1100-1101. 64. Syntheses, structures, photoluminescence and theoretical studies of d metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate Zheng, S.-L.; Yang, J.-H.; Yu, X.-L.;Chen, X.-M., W.-T. Wong, Inorg. Chem. 2004, 43, 830-838. 65. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209. 2003 66. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202. 67. Syntheses, structures, photoluminescence and theoretical studies of a novel class of d metal complexes of 1H-[1,10]phenanthrolin-2-one Zheng, S.-L.; Zhang, J.-P.; Chen, X.-M.; Huang, Z.-L.; Lin, Z.-Y.; Wong, W.-T.,Chem. Eur. J. 2003, 9, 3888-3896. 68. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.;Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883. 2002 69. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions Chen, X.-M.; Liu, G.-F., Chem. Eur. J. 2002, 8, 4811-4817. 70. Pseudo-polyrotaxane and b-sheet layer-based three-dimensional coordination polymers constructed with silver(I) salts and flexible pyridyl-type ligands Tong, M.-L.; Wu, Y.-M.; Ru, J.; Chen, X.-M., H.-C. Chang, Kitagawa, S., Inorg. Chem. 2002, 41, 4846-4848. 71. Metal cation-supported supramolecular crown ethers featuring hydrogen-bonded tetrameric unit of 2-hydroxy pyridines Tong, M.-L.; Lin, Z.-J.; Li, W.; Zheng, S.-L.; Chen, X.-M., Cryst. Growth Des. 2002, 2, 443-448. 72. Microwave-assisted elemental-direct-reaction route to nanocrystalline copper chalcogenides CuSe and Cu2Te Zhang, Y.; Qiao, Z.-P.;Chen, X.-M.,J. Mater. Chem. 2002, 12, 2747-2748. 73. Syntheses, crystal structures and physical properties of dinuclear copper(I) and tetranuclear mixed valence copper(I,II) complexes with hydroxylated bipyridyl-like ligands Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Lee, H.K.; Luo, L.; Li, J.-H.; Tong, Y.-X.; Chen, X.-M., Chem. Eur. J. 2002, 8, 3187-3194. 74. Interlocking of molecular rhombi into 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)]2×H2O (bpa = biphenyl-4,4¢-dicarboxylate, phen = 1,10-phenanthroline)Liu, G.-F.; Ye, B.-H.; Ling, Y.-H.; Chen, X.-M.,Chem. Commun. 2002, 1442-1443. 75. A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions Tao, J.; Zhang, Y.; Tong, M.-L.; Chen, X.-M., Yuen, T.; Lin, C.L.; Huang, X.-Y.; Li, J.,Chem. Commun. 2002, 1342-1343. 76. Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form Tong, M.-L.; Lee, H.K.; Tong, Y.-X.; Zheng, S.-L.; Shi, J.-X.; Chen, X.-M., Dalton Trans. 2002, 1727-1734. 77. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031. 78. One-pot monomer self-assembly route to thin coatings core/shell PbS/poly(methyl methacrylate) nanocomposites Qiao, Z.-P.; Xie, G.; Huang, J.-M.; Zhao, S.-Y.; Chen, X.-M.,J. Mater. Chem. 2002, 12, 611–613. 79. Self-assembly of new three-dimensional molecular architectures constructed from silver(I)-hexamethylenetetramine layers with supramolecular interactions Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.;Ng, S.W.,Dalton Trans. 2002, 360-364. 2001 80. Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dicarboxylates with hexamethylenetetramine exhibiting unique metal-p interaction Zheng, S.-L.; Tong, M.-L.; Tan, S.-D.; Wang, Y.; Shi, J.-X.; Tong, Y.-X.; Lee, H.K.; Chen, X.-M., Organometallics 2001, 20, 5319-5325. 81. Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits Chen, H.-J.; Mao. Z.-W.; Gao, S.; Chen, X.-M.Chem. Commun. 2001, 2320-2321. 82. A blue photoluminescent three-dimensional coordination polymer constructed with helical [Zn3(µ3-OH)(µ2-OH)]¥ chains and mixed organic ligandsTao, J.; Tong, M.-L.; J.-X. Shi, Chen, X.-M.,Inorg. Chem. 2001, 40, 6328-2330. 83. A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates Cai, J.-W.; Chen, C.-H.; Feng, X.-L.; Liao, C.-Z.; Chen, X.-M.,Dalton Trans. 2001, 2370–2375. 84. The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2] Zhang, X.-M.; Tong, M.-L.; Feng, S.-H.; Chen, X.-M., Dalton Trans. 2001, 2069-2070. 85. Syntheses and structures of three two-dimensional silver(I)-hexamethylenetetramine coordination polymers with new topologic motifs Zheng, S.-L.; Tong, M.-L.; Zhu, H.-l.; Fang, Y.; Chen, X.-M., Dalton Trans. 2001, 2049-2053. 86. Toward designed assembly of microporous coordination networks constructed from the silver(I)-hexamethylenetetramine layers Zheng, S.-L.; Tong, M.-L.; Fu, R.-W.; Chen, X.-M., S.W. Ng, Inorg. Chem. 2001, 40, 3562-3569. 87. Hydrogen bonds induced change of geometry and crystallized form of copper(II) complexes: syntheses and crystal structure of copper(II) complexes with Schiff-base ligands containing two imidazolyl groupsLong, L.-S.; Cai, J.-W.; Ren, Y.-P.; Tong, Y.-X.; Chen, X.-M.; Ji, L.-N.; Huang, R.-B.; Zheng, L.-S., Dalton Trans. 2001, 845-849. 88. A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4¢-bpy)]n layers and V4O12pillars Tao, J.; Zhang, X.-M.; Tong, M.-L.; Chen, X.-M.,Dalton Trans.2001,770-771. 89. Syntheses and structures of six chain-, ladder- and grid-like coordination polymers constructed from m-hexamethylenetetramine and silver salts Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Dalton Trans. 2001, 586-592. 90. Syntheses and crystal structures of four metal-organic coordination networks constructed form cadmium(II) thiocyanate and nicotinic derivatives with hydrogen bonds Yang, G.; Zhu, H.-G.; Liang, B.-H.; Chen, X.-M.,Dalton Trans. 2001, 580-585. 91. Syntheses and crystal structures of five two-dimensional networks constructed from staircase-like silver(I) thiocyanate chains and bridging polyamines Ren, C.-X.; Zhu, H.-L.; Yang G.;Chen, X.-M., Dalton Trans. 2001, 85-90. 2000 92. Influence of ligand backbones and counter ions on structures of helical silver(I) complexes with di-Schiff bases derived from phthalaldehydes and diamine Zhu, H.-L.; Tong, Y.-X.;Chen, X.-M.,J. Chem. Soc., Dalton Trans. 2000, 4182-4186. 93. Hydrothermal synthesis and crystal structures of [M(tp)(4,4’-bipy)] (M = Co(II), Cd(II) and Zn(II)): Three-dimensional coordination frameworks constructed with mixed terephthalate (tp) and 4,4’ bipyridine (4,4’-bipy) ligands Tao, J.; Tong, M.-L.; Chen, X.-M., J. Chem. Soc.,Dalton Trans. 2000, 3669-3674. 94. Blue photoluminescent zinc co-ordination polymers with supertetranuclear coresTao, J.; Tong M.-L.; Shi, J.-X.; Chen, X.-M., Ng, S.W., Chem. Commun. 2000, 2043-2044. 95. An octanuclear copper(II) complex self-assembled with divalent gem-diol form anion of di-2-pyridyl ketone (dpd-2H) and 2-hydroxylpyridine. Synthesis, crystal structure and properties of [Cu8(dpd-2H)4(m2-O2CMe)4{2-(OH)C5H4N}4](ClO4)4×4H2O Tong, M.-L.; Lee, H. K.; Tong, Y.-X.;Chen, X.-M.; Mak, T.C.W., Inorg. Chem. 2000, 39, 4666-4669. 96. Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different small simple silver(I) salts Tong, M.-L.; Zheng, S.-L.; Chen, X.-M., Chem. Eur. J. 2000, 6, 3729-3638. 97. Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]×6H2O Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Chem. Commun. 2000, 1817-1818. 98. Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, structures and non-linear optical properties of [4,4’-bipyH2][M(NCS)4] (M = Mn, Co and Zn; 4,4’-bipy = 4,4’-bipyridine) Chen, H.-J.; Zhang, L.-Z.; Cai, Z.-G.; Yang, G.;Chen, X.-M., J. Chem. Soc. Dalton Trans. 2000, 2463-2467. 99. Influence of the counter-ions and ligands on structures of silver(I) helicates with di-Schiff bases containing imidazole groups Yang, S.-P.; Chen, X.-M.; L.-N. Ji, J. Chem. Soc., Dalton Trans. 2000, 2337-2344. 100. Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4’-bpy)3(H2O)2(phba)2](NO3)2×4H2O (M = Cu2+ or Co ; 4,4’-bpy = 4,4’-bipyridine; phba = 4-hydroxybenzoate) Tong, M.-L.; Chen, H.-J.; Chen, X.-M.,Inorg. Chem. 2000, 39, 2235-2238. 101. Anionic and neutral metal-4,4’-bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4’-bipyridineTong, M.-L.; Chen, X.-M.,CrystEngCom 2000, 1. 1999 102. A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4’-bipyridine)2(H2O)4] cations and rich solvate 4,4’-bipyridine molecules throughhydrogen- bonding and p-p interactions Tong, M.-L.; Lee, H. K.; Chen, X.-M.; Huang, R.-B.; Mak, T.C.W.,J. Chem. Soc. Dalton Trans. 1999, 3657-3659. 103. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N.Angew. Chem. Int. Ed. 1999, 38, 2237-2240. 104. Synthesis and structures of carboxylate-bridged polynuclear copper(II)-lanthanide(III) complexes [CuLn(pyridinioacetate)5(H2O)5](ClO4)5·2H2O and [Cu3Nd2(pyridinioacetate)10(NO3)2(H2O)8](ClO48·4H2O Yang, Y.-Y.; Wu, Y.-L.; Long, L.-S.; Chen, X.-M., J. Chem. Soc., Dalton Trans. 1999, 2005-2008. 105. Synthesis, crystal structures and properties of copper(II) complexes of Schiff base derivativescontaining imidazole and b-alanine groups Long, L.-S.; Yang, S.-P.; Tong, Y.-X.; Mao, Z.-W.; Chen,X.-M.; Ji, L.-N.J. Chem. Soc., Dalton Trans. 1999, 1999-2004. 106. Two- and three-dimensional non-interpenetrating open-networks self-assembled by m4 hexamethylene-tetramine (hmt). Syntheses and structures of [Ag2(m4-hmt)(SO4)(H2O)]×4H2O and [Ag2(m4-hmt)(m2-O2CMe)](MeCO2)×4.5H2O Tong, M.-L.; Zheng, S.-L.; Chen, X.-M., Chem. Commun. 1999, 561-562. 1998 107. Synthesis, structures and magnetic properties of carboxylate-bridged tetranuclear copper(II)-lanthanoid(III) complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10·2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8Chen, X.-M.; Wu, Y.-L.; Yang, Y.-Y; Aubin, S.M.J.; Hendrickson,D.N. Inorg. Chem. 1998, 37, 6186-6191. 108. Helical silver(I)-2,4'-bipyridine chains organized into 2-D networks by metal-counterion or metal- metal bonding. Structures of [Ag(2,4'-bipyridine)]X (X = NO or ClO) Tong, M.-L.; Chen, X.-M.; Ye, B.-H.;Ng, S.W., Inorg. Chem. 1998, 37, 5278-5281. 109. Clathration of two-dimensional coordination polymers: Syntheses and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2](ClO4)4×(4,4'-H2bpy) (M = Cd, Zn, bpy = bipyridine)Tong, M.-L.; Ye, B.-H.; Cai, J.-W.; Chen, X.-M., Ng, S.W., Inorg. Chem. 1998, 37, 2645-2650. 110. A novel two-dimensional rectangular network. Synthesis and structure of {[Cu(4,4'-bpy)(pyz)(H2O)2](PF6)2}n (4,4'-bpy = 4,4'-bipyridine, pyz = pyrazine) Tong, M.-L.; Yu, X.-L.; Chen, X.-M.; Mak, T.C.W., J. Chem. Soc., Dalton Trans. 1998, 5-6. 1994 - 1997 111) The first metal-encapsulating star polysulphoxide incorporating 2-amino-1,3,4-thiadiazoleYang, C.; Chen, X.-M.; Lu, X.-Q.; Zhou, Q.-H.; Yang, Y.-S., J. Chem. Soc., Chem. Commun. 1997, 2041-2042. 112. Model complexes for the carboxylate-histidine-metal triad systems in metalloenzymes. Synthesis, crystal structures and spectroscopic properties of [M(Him)2(O2CMe)2] (M = ZnII or CoII, Him = imidazole). Chen, X.-M.; Ye, B.-H.; Huang, X.-C.; Xu, Z.-T.,J. Chem. Soc., Dalton Trans. 1996, 3465-3468. 113. Novel octadecanuclear copper(II)-lanthanoid(III) clusters. Synthesis and structures of [Cu12Ln6(m3-OH)24(O2CCH2CH2NC5H5)12(H2O)16(m12-ClO4)](ClO4)17·16H2O (Ln = Gd or Sm)Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Huang, X.-Y., J. Chem. Soc., Dalton Trans. 1996, 2443-2448. 114. Synthesis, crystal structure and luminescence properties of a europium(III) complex with a new planar aromatic tridentate N3 ligand Yang, C.; Chen, X.-M.; Zhang, W.-H.; Chen, J.; Yang, Y.-S.; Gong, M.-L.,J. Chem. Soc., Dalton Trans. 1996, 1767-1768. 115. Synthesis and structure of a novel carboxylate-bridged heterometallic copper(II)-gadolinium(III) complex Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J.,J. Chem. Soc.,Dalton Trans. 1996, 2181-2182. 116. Synthesis, structure and magnetic properties of a singly carboxylato-bridged dinuclear Mn(II) complex Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T.C.W.,J. Chem. Soc.,Dalton Trans. 1995, 4001-4004. 117. Polynuclear Cu12-M6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion: [Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine) Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601. 118. A model complex for the carboxylate-histidine-zinc system in zinc enzymes. Crystal structure of [Zn(Him)2(MeCO2)2] (Him = imidazole)Chen, X.-M.; Xu, Z.-T.; Huang, X.-C., J. Chem. Soc., Dalton Trans. 1994, 2331-2332. 119. A dinuclear zinc complex of biological relevance. Crystal structure of [Zn2(bpy)2(MeCO2)3]ClO4Chen, X.-M.; Tong, Y.-X.; Mak, T.C.W., Inorg. Chem. 1994, 33, 4586-4588.
2 北京外国语大学副教授◎ 个人简介男,1962年出生,广西北海合浦人,副教授。1988年7月毕业于广西师范学院中文系,获学士学位;1995年7月毕业于南开大学中文系,获硕士学位;2000年7月毕业于南开大学中文系,获博士学位。1995年7月至1997年9月,在北京语言大学汉语速成学院任教;2000年8月至今,任教于北京外国语大学国际交流学院。 主要研究方向为现代汉语词汇、语法和方言。 ◎ 项目成果先后在语文建设、天津社会科学、陕西师范大学学报等刊物发表了方式宾语初探、量词表量的方式及表量大小与肯定否定的关系、汉语姓名称呼的类别、功能及其使用情况、粤方言"量+名"结构的再考察、现代汉语爱称研究、广州话詈称初探、"一级"高还是"九级"高?--汉语"数+级"表等级的特点和用法、粤方言"?唪唥"再探、粤语量词的表量方式、对粤方言"形+量"组合的一些认识、粤方言量词"只"的虚化等十余篇论文,还参加编写了汉语普通话教程精读课本等教材。 3 城步第一民族中学教师1954年9月生,湖南城步人,大学文化,城步第一民族中学高级教师,中国教育写作学会会员,全国中小学语文教学研究会会员,《全国青少作文精品》杂志社常务编委,《全国中小学生文学社团作品集粹》编委,全国"三侠"研究中心常务理事。主要著作有;《快速作文入门指导》、《小学作文新题指导与示范》、《初中作文新题指导示范》、《中考作文教师示范集》、《中学作文应试范例》、《快速作文指导跨。在各级刊物上发表文章40余篇,其中《口头作文与快速作文结合,课内作文与课外作文结合》于1994年在全国首届快速作文研讨会上做了经验介绍,荣获全国基础教育优秀教改新成果二等奖、市一等奖、省二等奖,被收编入《中国语文教学研究新成果全书》;《利用口头作文加强对学生的思想教育》于1992年在《人民教育》第8期上发表,并被收编入《教师优秀论文集》。1998年12月应邀在香港教育学院参加了国际语文教育研讨会,在大会上作了题为《快速能力训练是提高语文教学效率的有效手段》专题发言。 4 江苏泰州制药总厂职员1959年3月生,江苏泰州人,结业于北京人文函授大学法律系,任职于泰州制药总厂。系中华全国集邮联合会会员、北京东方收藏家协会会员、中国万变诗集研究会及天下奇迹创造者学会副会长、《中国当代集藏家辞典》编委、《天下奇迹创造者大全》副主编等。自幼喜爱猎奇和收藏,通信交友遍及全国。擅长写作。主集世界各国国名、地名邮票,以研究相关政治、经济、历史、地理知识;兼集新中国邮票邮品、中外钱币、名人名片、徽章、领带夹、粮票等。多次参加藏品展览,并参与设计制作多种纪念邮品。曾连续数年被评为市级集邮先进个人。传略已入编《中国集邮名家辞典》、《中国当代文艺界人名大辞典》、《当代诗家代表作手迹·传略宝典》等。 5 四川省律师协会常务理事陈小明,男,1965年5月生,日语学士,法学硕士,1995年12月起在四川华川正大律师事务所执业,1999年12月发起成立四川金座标律师事务所,任合伙人、主任,2006年3月发起成立四川尺度律师事务所,任合伙人、主任。四川省律师协会常务理事,四川省海峡两岸法律研究会常务理事、副秘书长。2002年获评“成都市优秀律师”;2003年获评“成都市优秀律师事务所主任”;2004年获评第二届“蓉城十佳律师”提名;2004年获评“四川省优秀律师”,2009年再度获评“四川省优秀律师”。 陈小明律师特别擅长投资银行、商业银行及其他金融法律,刑事法律和公司法律。从事律师职业以来,陈小明律师先后担任中国银行四川省分行、中国华融资产管理公司成都办事处、华西证券、四川汇源科技集团、四川省中医药研究院等数十家机关、事业单位和大、中型企业法律顾问,为这些单位防范法律风险作出了积极的贡献。在诉讼法律服务领域,陈小明律师先后承办了数十起重大经济纠纷案件,为当事人避免了十多亿经济损失。在非诉讼法律服务领域,陈小明律师先后承办了二十多宗企业改制、并购重组案件,在资本运作、改制重组和国际国内融资领域积累了丰富的经验。 6 湖南大学体育学院教师陈小明 1976年毕业于武汉体育学院,分配到长沙市体委担任篮球教练员工作。期间:曾担任湖南省女子篮球队主教练,长沙市女子篮球队主教练,长沙市少年男、女篮球队主教练,均取得了一些好成绩,1990年,被长沙市政府授予“立大功”一次。2000年调入湖南大学,担任湖南大学女子篮球队主教练。后担任篮球公体课的教学工作。 7 江西省江宁物流有限公司总经理陈小明(1964.3-)江西省宁都县黄陂镇高田村人。1983年12月应征入伍,在云南某部队服役。1986年1月在家乡做生意。1988年2月起在广东珠海务工。1993年1月在珠海开办鞋厂并任厂长。1996年1月在广东省中山市创办江西省江宁物流有限公司并任总经理。 8 台湾歌仔戏演员◎ 百科名片陈小明,台湾歌仔戏演员、制作助理/节目助理。是“杨丽花歌仔戏团”主要演员之一,参与不少歌仔戏剧目的演出,也是杨丽花歌仔戏团的制作助理/节目助理。 ◎ 电视歌仔戏台视 杨丽花歌仔戏团 1982年 《杨家将》 饰 呼鲁图 1983年 《万花楼》又名《万花楼与狄青》 饰 胡伦、韩福、钦差 1984年 《梁山伯与祝英台》 饰 奴才 1985年 《韩信》 饰 黄石公 1985年12月30日 《挚剑双骄》 饰 老猴伯 1987年04月23日 《王文英与竹芦马》 饰 陈渊 1987年10月19日 《朱洪武》 饰 陈员外、店小二、蛮子 1988年07月04日 《李靖与红拂女》又名《李靖斩龙》 饰 萧国舅、苦命老人 1989年 《红楼梦》又名《金陵十二钗》 饰 和尚 1989年07月13日 《泥马渡康王》又名《红粉佳人》 饰 张叔夜 1990年05月21日 《伴鬼闯江湖》又名《福星闯江湖》 饰 乙鬼 1991年 《新狄青》又名《狄青取旗》 饰 相士/鬼谷子、脱伦 1992年 《巡按与大盗》 饰 老师、将军、乞丐 9 安徽省安庆市怀宁县小学校长◎ 陈小明男,汉族,1970年7月出生,中共党员,大专学历,1990年毕业于怀宁师范。现任安庆市小语会理事,怀宁县公岭镇纪委委员、中心学校副校长,小学语文高级教师。 ◎ 工作简历1990~1998年任公岭小学教导副主任、少先大队辅导员。 1999~2002年任公岭中心小学教导副主任。 2003年任公岭中心小学教导主任。 2004年至今任公岭中心学校副校长,分管德育团队、教师培训、体育卫生、教育科研等工作。 ◎ 学习简介2002年参加电大小教(文史)学习,取得专科学历。 2005年8月参加“英特尔未来教育”培训,取得合格证书。 2006年参加怀宁县校长培训班。 2008年参加安徽省网络校长培训班并被评为“优秀学员”。 2009年4月至6月挂职学习于安庆石化三小。2009年10月至2010年2月抽调到镇“学习实践科学发展观”活动办公室学习。 2010年11月参加“国培计划”培训并管理“安庆语文四班”怀宁片区100名教师网上培训工作。 ◎ 工作成绩2001年论文《从新大纲浅谈作文教学》、教师下水文《家乡的变化》均获国家级三等奖。 2004年9月被评为怀宁县首届“小学语文学科带头人”、“骨干教师”。 2004年12月《<爸爸和书>教学实录和反思》获安庆市案例评选三等奖。 2007年1月被评为市级骨干教师。7月个人主页《放飞梦想》获安庆市教师教育技术优秀作品二等奖。 2009年8月论文《文本细读深入浅出》获安庆市三等奖并载入《小学语文课改实践与探索》一书。12月《特色学校创建的认识与思考》获“中国●安庆市中小学校长论坛”论文评选二等奖。 2010年10月教师博客《展翅雄雄鹰》获县级二等奖。 2011年7月在实施“国培计划”中,本人管理的“安庆语文四班”获得安徽省“活跃班级”称号,同时被评为全国“优秀班级”。 |
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