| 词条 | 沃氏实用有机化学教程 |
| 释义 | 图书信息出版社: 世界图书出版公司; 第1版 (2004年1月1日) 外文书名: Vogel's Textbook of Practical Chemistry 5th ed. Vo1.1 平装: 823页 正文语种: 英语 开本: 24 ISBN: 7506265842 条形码: 9787506265843 尺寸: 22 x 14.6 x 4 cm 重量: 975 g 内容简介《沃氏实用有机化学教程(第1卷)(第5版)》内容简介：This is the second time that we have prepared a new edition of Vogel's Textbook of Organic Chemistry and it is important to reaffirm the aims set out by the late Dr A. I. Vogel in the preface to the first edition. Thus in this new edition every endeavour is made to retain the comprehensive character of the book, and to ensure that it continues to be a one-volume reference text which is of value to practising organic chemists throughout their undergraduate, postgraduate and subsequent careers. 目录CHAPTER 1 ORGANIC SYNTHESIS 1.1 INTRODUCTION 1.2 STRUCTURE OF THE TARGET MOLECULE 1.3 REACTION MECHANISM AND THE METHODOLOGY OF SYNTHESIS 1.4 REACTION MECHANISM AND THE STRATEGY OF SYNTHESIS 1.5 CONCLUSION REFERENCES CHAPTER 2 EXPERIMENTAL TECHNIOUES 2.1 GENERAL INSTRUCTIONS FOR SAFE WORKING IN ORGANIC CHEMICAL LABORATORIES 2.2 PLANNING OF EXPERIMENTS AND RECORDING OF RESULTS 2.3 HAZARDS IN ORGANIC CHEMISTRY LABORATORIES APPARATUS AND REACTION PROCEDURES 2.4 INTERCHANGEABLE GROUND GLASS JOINTS 2.5 TYPES OF GROUND GLASS JOINTS 2.6 CARE AND MAINTENANCE OF GROUND GLASS JOINTS 2.7 APPARATUS WITH INTERCHANGEABLE GROUND GLASS JOINTS SUITABLE FOR GENERAL USE IN PREPARATIVE ORGANIC CHEMISTRY 2.8 OTHER TYPES OF INTERCHANGEABLE JOINTS AND STOPCOCKS 2.9 THE USE OF CORKS AND RUBBER STOPPERS 2.10 CUTTING AND BENDING OF GLASS TUBING 2.11 GENERAL LABORATORY APPARATUS 2.12 COOLING OF REACTION MIXTURES 2.13 JEATOMG PF REACTOPM MIXTIRES 2.14 MECJAMOCAL AGOTATION 2.15 TYPICAL GROUND GLASS JOINT ASSEMBLIES FOR STANDARD REACTION PROCEOURES 2.16 PRECAUTIONS FOR UNATTENEDE REACTINS 2.17 APPARATUS FOR SPECIAL REACTION TECHNIQUES ISOLATION AND PURIFICATION PROCESSES 2.18 GENERAL CONSIDERATIONS 2.19 FILTRATION TECHNIQUES 2.20 RECRYSTALLISATION TECHNIQUES 2.21 SUBLIMATION TECHNIQUES-FREEZE DRYING 2.22 SOLVENT EXTRACTION 2.23 DRYING OF LIQUIDS OR OF SOLUTIONS OF ORGANIC COMPOUNDS IN ORGANIC SOLVENTS 2.24 DISTILLATION AT ATMOSPHERIC PRESSURE 2.25 STEAM DISTILLATION 2.26 FRACTIONAL DISTILLATION AT ATMOSPHERIC PRESSURE 2.27 DISTILLATION UNDER DIMINISHED PRESSURE ('VACUUM' DISTILLATION) 2.28 HIGH VACUUM DISTILLATION - MOLECULAR DISTILLATION 2.29 VACUUM PUMPS 2.36 MANOMETERS, VACUSTATS, VACUUM GAUGES AND MANOSTATS 2.31 CHROMATOGRAPHY 2.32 STORAGE OF SAMPLES 2.33 MELTING POINT - MIXED MELTING POINTS 2.34 DETERMINATION OF BOILING POINT 2.35 DETERMINATION OF MOLECULAR WEIGHT 2.36 DETERMINATION OF OPTICAL ROTATORY POWER 2.37 DETERMINATION OF REFRACTIVE INDEX REFERENCES CHAPTER 3 SPECTROSCOPIC METHODS AND THE INTERPRETATION OF SPECTRA Introduction The electromagnetic spectrum 3.1 INFRARED SPECTROSCOPY Instrumental features of infrared spectrophotometers Determination of infrared spectra Sample preparation Features of an infrared spectrum Interpretation of an infrared spectrum Characteristic group frequencies 3.2 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY Features of the nuclear magnetic resonance spectrum The chemical shift Spin-spin splitting Protons attached to heteroatoms Simplification of 'H spectra Interpretation of the p.m.r, spectrum Further information from 13 C-spectra 3.3 MASS SPECTROMETRY The mass spectrum Appearance of the mass spectrum Interpretation of the mass spectrum Mass spectra of classes of organic compounds 3.4 ULTRAVIOLET-VISIBLE SPECTROSCOPY Instrumental features of ultraviolet-visible spectrophotometers Determination of ultraviolet-visible spectra Laws of light absorption Solvents for ultraviolet spectroscopy Solution preparation Optical cells and their care Features of an ultraviolet-visible spectrum REFERENCES CHAPTER 4 SOLVENTS AND REAGENTS 4.1 THE PURIFICATION OF COMMON ORGANIC SOLVENTS Saturated aliphatic hydrocarbons Aromatic hydrocarbons Halogenated hvdrocarbons Aliphatic alcohols Ethers Ketones Esters Nitrogen-containing solvents Sulphur-containing solvents Phosphorus-containing solvents 4.2 THE PREPARATION AND PURIFICATION OF REAGENTS REFERENCES CHAPTER 5 ALIPHATIC COMPOUNDS 5.1 ALKANES Structure Summary of preparative methods and of retrosynthetic strategies Spectroscopic features 5.1.1 The catalytic hydrogenation and chemical reduction of alkenes 5.1.2 The hvdrolysis of alkylmagnesium halides and the hydrogenolysis of alkyl halides and of alkyl methane- or toluene-p-suiphonates 5.1.3 The reduction of aldehydes and ketones 5.1.4 Coupling reactions (a) using organometallic compounds, and (b) at the anode 5.2 ALKENES Structure Summary of preparative methods and of retrosynthetic strategies Spectroscopic features 5.2.1 1,2-Elimination processes ([i-elimination) 5.2.2 The partial hydrogenation of aikynes 5.2.3 Wittig and related reactions 5.2.4 Selected rearrangements of alkynes to allenes 5.3 ALKYNES Structure Summary of preparative methods and of retrosynthetic strategies Spectroscopicfeatures 5.3.1 The dehydrogenation of vic- and gem-dihalides 5.3.2 The oxidation of dihydrazones of 1,2-diketones 5.3.3 Aikylation of a terminal alkyne 5.3.4 Coupling reactions leading to diynes 5.4 ALIPHATIC ALCOHOLS Structure Summary of preparative methods and of retrosynthetic strategies Spectroscopicfeatures 5.4.1 The reduction of aldehydes, ketones and esters 5.4.2 The interaction of carbonyl-containing compounds with organometallic reagents 5.4.3 The hydroboration-oxidation of alkenes 5.4.4 The oxymercuration-demercuration of alkenes 5.4.5 The hydroxylation of alkenes 5.4.6 Methods for the protection of the hydroxyl group …… CHAPTER 6 AROMATIC COMPOUNDS CHAPTER 7 SELECTED ALICYCLIC ALICYCLIC COMPOUNDS CHAPTER 8 SELECTED HETEROCYCLIC COMPOUNDS CHAPTER 9 INVESTIGATION AND CHARACTERISATION OF ORGANIC COMPOUNDS CHAPTER 10 PHYSICAL CONSTANTS OF ORGANIC COMPOUNDS APPENDICES Table of atomic weights Index Reference data Abbreviations |
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