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词条 李超忠
释义

个人简历

李超忠,男,1968年5月生于福建省福安市,现为中国科学院上海有机化学研究所研究员,课题组组长。入选1999年度中科院“百人计划”,并在终期考核中评为优秀“百人计划”。获2003年度“国家杰出青年科学基金”、2004年度“吴蕴初奖”提名奖、2006年度国家政府特殊津贴。

教育经历

1983.9 – 1988.7: 中国科学技术大学应用化学系,学士

1988.9 – 1993.7: 中国科学院上海有机化学研究所,博士

1993.8 – 1994.5: 中国科学院上海有机化学研究所,助理研究员

1994.6 – 1998.12: 美国Iowa State University化学系,博士后

1999.1 – 1999.12: 中国科学院上海有机化学研究所, 副研究员

2000.1至今: 中国科学院上海有机化学研究所, 研究员

研究方向

导向有机合成的自由基反应研究

自由基环合反应 - 内酯、内酰胺及环酮的高选择性合成

芳烃及烯烃金属络合物的自由基反应

自由基反应在天然产物合成中的应用

电子转移参与的自由基反应

在研基金

“国家杰出青年科学基金”:

(20325207) 自由基化学。2004年1月至2007年12月。

国家自然科学基金:

酰胺氮自由基环合反应研究(20472109)。 2005年1月至 2007年12月。

烯烃金属络合物的自由基反应研究(20672136)。2007年1月至 2009年12月。

学术兼职

中国科技大学和同济大学兼职博士生导师

课题组现有人员

19名研究生(包括联合培养),2名博士后,8名职工。

学术业绩

Invited Lectures:

1. Organic Free Radicals in Biology and Synthesis, Pacifichem2005, Honolulu, Hawaii, USA, December 17, 2005.

2. 2nd Pacific Symposium on Radical Chemistry, KAIST, Daejeon, Korea, November 5-8, 2006.

3. 2007 Gordon Research Conference on Radicals and Radical Ions in Chemistry and Biology, Plymouth, NH, USA, July 1-6, 2007.

4. 10th International Symposium on Organic Free Radicals, Heron Island, Australia, August 3-9, 2008.

Selected Publications(部分):

1. Xinting Yuan and Chaozhong Li*, Development of Highly Regioselective Amidyl Radical Cyclization Based on Lone Pair – Lone Pair Repulsion, in preparation for J. Org. Chem.

2. Pinhong Chen, Junhua Wang*, Kun Liu and Chaozhong Li*, Synthesis and Structural Revision of (±)-Laurentristich-4-ol, J. Org. Chem., submitted.

3. Feng Liu, Kun Liu, Xinting Yuan and Chaozhong Li*, 5-Exo versus 6-Endo Cyclization of Primary Aminyl Radicals: An Experimental and Theoretical Investigation, J. Org. Chem., accepted.

4. Xinqiang Fang, You-Cheng Liu*, and Chaozhong Li*, 9-Phenyl-10-methylacridinium: A Highly Efficient and Reusable Organocatalyst for Mild Aromatization of 1,4-Dihydropyridines by Molecular Oxygen, J. Org. Chem. 2007, 72, ASAP.

5. Tianshun Hu, Kun Liu, Meihua Shen, Xinting Yuan, Yu Tang and Chaozhong Li*, O-Attack versus N-Attack: Electrophilic Halocyclization of Unsaturated Amides with Vinylic Halogen Substitution, J. Org. Chem. 2007, 72, ASAP.

6. Yewen Fang and Chaozhong Li*, Preference of 4-Exo Ring Closure in Copper-Catalyzed Intramolecular Coupling of Vinyl Bromides with Alcohols, J. Am. Chem. Soc. 2007, 129, 8092-8093.

7. Yuanjia Pan, Hongjian Lu, Yewen Fang, Xinqiang Fang, Liqun Chen, Junlu Qian, Junhua Wang and Chaozhong Li*, Synthesis of Pyrroles via Copper-Catalyzed Coupling of Amines with Bromoenones, Synthesis 2007, 1242-1246. (Invited paper)

8. Hongjian Lu, Qian Chen and Chaozhong Li*, Control of the Regioselectivity of Sulfonamidyl Radical Cyclcization by Vinylic Halogen Substitution, J. Org. Chem. 2007, 72, 2564-2569.

9. Qian Chen and Chaozhong Li*, Activation of Vinylic C-Cl Bond by Complexation of Fe(CO)3: Palladium-Catalyzed Coupling Reactions of (h4-Chlorodiene)tricarbonyliron Complexes, Organometallics 2007, 26, 223-229.

10. Hongjian Lu and Chaozhong Li*, General and Highly Efficient Synthesis of 2-Alkylideneazetidines and b-Lactams via Copper-Catalyzed Intramolecular N-Vinylation, Org. Lett. 2006, 8, 5365-5367.

11. Yewen Fang and Chaozhong Li*, O-Arylation versus C-Arylation: Copper-Catalyzed Intramolecular Coupling of Aryl Bromides with 1,3-Dicarbonyls, J. Org. Chem. 2006, 71, 6427-6431.

12. Tianshun Hu, Meihua Shen, Qian Chen and Chaozhong Li*, Pushing Radical Cyclization from Regioselective to Regiospecific: Cyclization of Amidyl Radicals Controlled by Vinylic Halogen Substitution, Org. Lett. 2006, 8, 2647-2650.

13. Hechun Lin, Qian Chen, Lidong Cao, Li Yang, Yun-Dong Wu* and Chaozhong Li*, Effect of M(CO)3 (M = Cr, Mn+) on Aromatic C-Cl BDE in (h6-ArCl)M(CO)3 Complexes, J. Org. Chem. 2006, 71, 3328-3331.

14. Lidong Cao, Meihua Shen and Chaozhong Li*, Indium-Mediated Alkyl Radical Addition to (h6-Arene)tricarbonylmanganese Complexes in Aqueous Media, Organometallics 2005, 24, 5893-5898.

15. Yewen Fang and Chaozhong Li*, CuI-Catalyzed Intramolecular O-Vinylation of Carbonyl Compounds, Chem. Commun. 2005, 3574-3576.

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