词条 | 过渡金属簇化学的最新进展 |
释义 | 基本信息过渡金属簇化学的最新进展 (英文版) 作者: 卢嘉锡 定价: ¥ 298.00 元 出版社: 科学出版社 出版日期: 2000年05月 ISBN: 7-03-007788-1/O·1152 开本: 16 开 类别: 无机化学化工,物理化学 页数: 485 页 简介 本书介绍由卢嘉锡领导的中国科学院福建物质结构研究所实验室20多年来取得的科研研成果,分别由刘春万,黄建全等研究员执笔,由卢嘉锡定稿稿,本成果数世界水平. 目录CHAPTERIIntroduction LiuChunWan 11TheHistoricalBackgroundofClusterChemistry 12ThePresentSituationofMetalClusterChemistry 13From"UnitConstructionHypothesis"to"UnitConstructionTheory" 14AromaticityandQuasiAromaticity 15NewAspectsofSyntheticChemistryofTransitionMetalCluster CompoundsReferencesCHAPTER2SurveyofStructuralRulesandTheoreticalRationalization ChenZhi'Da 21Introduction 22StructuralTrendofTransitionMetalClusters 23GeneralSurveyofStructuralRules 24TheoreticalRationalizationfortheStructuralRules References CHAPTER3UnitConstructionTheoryofMetalClusterCompounds ZhuangBotao,WuXinTao,ChenWen'Dan,HuangJinShun,LiuChun'Wan andLuJiaXi 31A"UnitConstructionApproach"totheRationalSynthesesofTransition MetalCubaneLikeClustersbytheUseofReactiveFragmentsasBuild ingBlocks 32DesignedSynthesisforSomeTransitionMetalClustersInvolving BridgingSuitidoLigands 33SynthesisofMetalClustersfromReactiveFragments 34TheReactivityTheoryofUnitConstructions References CHAPTER4ANewTypeofAromaticity HuangJianQuan,ChengWenDon,ChenZhi'Da,LiJun,LiuChun'Wanand LuJiaXi 4IExperimentalEvidencesofQuasiAromalicityintheMo(8)3Ring 42TheBondingModelandtheBondingPropertiesofClusterCores M3(X)3(M=Mo,W;X0,S,CI,Br) 43LocalizedMolecularOrbitalStudiesontheQuasiAromaticity 44AhInitioStudiesonQuasiAromaticity References CHAPTER5BondingPropertiesoftheMM'XTransitionMetalClusterCompounds LiuChunWanandChengWenDan 51Introduction 52BondingPropertiesoftheMoFe~SclusterCompounds 53BondingCharacteristicsoftheEarlyTransitionMetalCluster Compounds 54StructuralRulesoftheTransitionMetalClusters |
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