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词条 过渡金属簇化学的最新进展
释义

基本信息

过渡金属簇化学的最新进展 (英文版)

作者: 卢嘉锡 定价: ¥ 298.00 元

出版社: 科学出版社 出版日期: 2000年05月

ISBN: 7-03-007788-1/O·1152 开本: 16 开

类别: 无机化学化工,物理化学 页数: 485 页

简介

本书介绍由卢嘉锡领导的中国科学院福建物质结构研究所实验室20多年来取得的科研研成果,分别由刘春万,黄建全等研究员执笔,由卢嘉锡定稿稿,本成果数世界水平.

目录

CHAPTERIIntroduction

LiuChunWan

11TheHistoricalBackgroundofClusterChemistry

12ThePresentSituationofMetalClusterChemistry

13From"UnitConstructionHypothesis"to"UnitConstructionTheory"

14AromaticityandQuasiAromaticity

15NewAspectsofSyntheticChemistryofTransitionMetalCluster

CompoundsReferencesCHAPTER2SurveyofStructuralRulesandTheoreticalRationalization

ChenZhi'Da

21Introduction

22StructuralTrendofTransitionMetalClusters

23GeneralSurveyofStructuralRules

24TheoreticalRationalizationfortheStructuralRules

References

CHAPTER3UnitConstructionTheoryofMetalClusterCompounds

ZhuangBotao,WuXinTao,ChenWen'Dan,HuangJinShun,LiuChun'Wan

andLuJiaXi

31A"UnitConstructionApproach"totheRationalSynthesesofTransition

MetalCubaneLikeClustersbytheUseofReactiveFragmentsasBuild

ingBlocks

32DesignedSynthesisforSomeTransitionMetalClustersInvolving

BridgingSuitidoLigands

33SynthesisofMetalClustersfromReactiveFragments

34TheReactivityTheoryofUnitConstructions

References

CHAPTER4ANewTypeofAromaticity

HuangJianQuan,ChengWenDon,ChenZhi'Da,LiJun,LiuChun'Wanand

LuJiaXi

4IExperimentalEvidencesofQuasiAromalicityintheMo(8)3Ring

42TheBondingModelandtheBondingPropertiesofClusterCores

M3(X)3(M=Mo,W;X0,S,CI,Br)

43LocalizedMolecularOrbitalStudiesontheQuasiAromaticity

44AhInitioStudiesonQuasiAromaticity

References

CHAPTER5BondingPropertiesoftheMM'XTransitionMetalClusterCompounds

LiuChunWanandChengWenDan

51Introduction

52BondingPropertiesoftheMoFe~SclusterCompounds

53BondingCharacteristicsoftheEarlyTransitionMetalCluster

Compounds

54StructuralRulesoftheTransitionMetalClusters

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