“崔秀玲”的意思、由来-中文百科全书

宁波市人大常委会副主任

崔秀玲，女，汉族，浙江鄞县人，1958年9月出生，本科学历，1981年8月参加工作。历任宁波市鄞县林业局副局长、鄞县人民政府县长助理、副县长、鄞州区人民政府副区长。现任宁波市人大常委会副主任。

郑州大学化学系研究生导师

Dr. Xiuling Cui

Full Professor, Chemistry Department, Zhengzhou University, 2008

Associate Professor, Chemistry Department, Zhengzhou University, 2002

The research in our group on Organometallic Chemistry combines techniques of organic synthesis, physical organic chemistry and organometallic chemistry. In recent years, C-C, C-N and C-O bond-forming processes have become among the most important reactions in the pharmaceutical and fine chemical industry. So we have been interested in the development of optimized catalytic processes, green catalyst and solvents to accomplish this important task. Our research involves the synthesis of metal complexes; development of environmentally catalytic processes; study on the novel chiral ligands for asymmetric synthesis; investigation on the kindly environmental catalytic system for important medicine intermediates.

Education and Training

Postdoctoral Research Associate:

09/2000-08/2006 Instituto de Tecnologia Quimica e Biologica, University Nova de Lisboa, Portugalwith Postdoctoral fellowship grand from Portuguese Ministry of Scientific and Technological with Professor Rita Delgado

Preparation and study of new molecules working as redox sensor for transition metal ions, bio-anions or bio-neutral molecules

Ph. D.:

(09/1996-07/1999) Department of Chemistry, Zhengzhou University, P. R. China

Supervisor: Professor, Academician, Yangjie Wu

Study on the cyclometallation of ferrocenylimines and relative stereochemistry aspect

M. Sc

(09/1993-07/1996) Department of Chemistry, Zhengzhou University, P. R. China

Supervisor: Professor, Academician, Yangjie Wu

Study on the cyclometallation of ferrocenylimines

B. S.

(09/89-07/93) Department of Chemistry, Zhengzhou University, P. R. China

Teaching:

Organic Chemistry, Organic Synthesis Experiment, Chemistry Specialty English

Research grant

Studies on the synthesis and application of chiral Aza-ferrocenophanes (手性氮杂二茂铁环番的合成及其应用研究, 国家自然科学资金20972139)

Studies on the palladacycles catalyzed C-C, C-heteratom bond forming and its mechanism （环钯化合物催化碳-碳、碳-杂原子键的生成及其机理研究，河南省自然科学资金082300423201)

Main Award

2004 Application of Cyclopalladated Complexes in Organic Synthesis, Research Fund award from Chinese National Personal Ministry

2003 Application of Cyclometallated Complexes in Organic Synthesis, Research Fund award from Chinese National Education Ministry

2002 Project: Cyclometallation Reaction and Intramolecular Coordination First-class award in advanced scientific and technological research warded by Henan Provincial government P.R. China

2001 Excellent Young Professor in Universities in Henan province

2000 to 2006 Postdoc. Grant from Portuguese Ministry of Scientific and Technological

Selected Publication

Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C-H Activation under External-Oxidant-Free Conditions，Junliang Wu, Xiuling Cui,* Lianmei Chen, Guojie Jiang, Yangjie Wu* J. Am. Chem. Soc,2009, 13888-13889Synthesis and Structure of Heteroannular Cyclopalladated Chiral Ferrocenylimines. Theoretical Interpretation of the Cyclopalladated Complexes Based on Density Functional Calculations Hengyu Qian,Xiuling Cui*, Mingsheng Tang, Chun Hui, Cheng Liu, Yangjie Wu*, New J. Chem2009，33，668-674Ferrocenylimidazoline Palladacycles as Efficient Catalysts for the Aza-Claisen Rearrangement Reaction of Allylic Imidates，Ji Ma, Xiuling Cui*, Dejian Yang, Junliang Wu,Maoping Song, Yangjie Wu*，App. Organomet. Chem., 2008, 624-628Ferrocenylimidazoline palladacycles: efficient phosphine-free catalysts for suzuki-miyaura cross-coupling reaction，Ji Ma, Xiuling Cui*, Bi Zhang, Maoping Song, Yangjie Wu，Tetrahedron,2007, 2007, 63(25) 5529-5538Cyclopalladated ferrocenylimines: efficient catalysts for homocoupling and sonogashira reaction of terminal alicynes, Fan Yang, Xiuling Cui, Yanan Li, Jinli Zhang, Gerui Ren and Yangjie Wu, Tetrahedron, 2007, 63, 1963-1969Ferrocenyl-imidazoline palladacycles: syntheses, crystal structures and applications as Suzuki cross coupling catalysts in water, Ji Ma, Xiuling Cui*, Liuyi Gao, Yangjie Wu*, Inorg. Chem. Commou.2007, 10(7), 762-766.Carboxylate anions recognition and sensing by novel receptor--- ferrocene functionalized polyamine, Xiuling Cui, Rita Delgado, Michael G. B. Drew, and Vitor Felix,Dalton Trans. 2005, 3297-3306Bis[1,1'-N,N'-(2-picolyl)aminomethyl]ferrocene as a Redox Sensor for Transition Metal Ions，Xiuling Cui, Helena Carapura, Rita Delgado，Michael G. B. Drew and Vítor Félix，DaltonTrans., 2004, 1743-1751.Complexation properties of a tetraazamacrocycle with phenol pendant arms: X-ray structures, spectroscopic and DFT studies, Xiuling Cui, Maria José Calhorda, Paulo J. Costa, Rita Delgado, Michael G. B. Drew and Vítor Félix，Helev. Chim. Acta., 2004, 2613-2628.Synthesis of Novel Chiral Tellurium Complexes by Redox Reaction of Planar Chiral Cyclomercurated Ferrocenylimines with Tellurium Powder and X-ray Crystal Structure of TeCl{C5H5FeC5H3C(CH3)=N-C6H4-4-CH3} Yangjie Wu, Liangru Yang, Xiuling Cui, Chenxia Du, Yu Zhu, Tetrahedron: Asymmetry, 2003, 14(8), 1073-1077. Invited Review: Studies on the cyclometallation of ferrocenylimines, Yangjie Wu, Shouquan Huo, Junfang Gong, Xiuling Cui, Li Ding, Kuiling Ding, Chenxia Du, Yuanhong Liu and Maoping Song, J. Organomet. Chem., 2001, 637-639, 27-46。Synthesis, isolation and structural characterization of optically active planar chiral cyclomercurated ferrocerylimines, Yangjie Wu, Xiuling Cui, Ning Zhou, Maoping Song, Hongying Yun, Chenxia Du, Yu Zhu, Tetrahedron: Asymmetry, 2000, 11, 4877.Transmetallation Reactions of Planar Chiral Cyclopalladated and Cyclomer-curated Ferrocenylimines with Metallic Tin, Yangjie Wu, Xiuling Cui, Jianjun Hou, Liangru Yang, Min Wang, Acta. Chim. Sinica, 2000, 58(7), 871. （For Academician Youqi Tang’s 80th birthday）Transmetallation reaction of planar chiral cyclopalladated ferrocenylimines with metallic mercury, Xiuling Cui, Yangjie Wu, Liangru Yang, Tetrahedron: Asymmetry, 1999, 10(7), 1255. Resolution of cyclopalladated ferrocenylketimines, Yangjie Wu, Xiuling Cui, Chenxia Du, Wenling Wang, Ruiyun Guo, Rongfeng Chen, J. Chem. Soc., Dalton Trans.,1998, 22, 3727. Cyclometallation of Ferrocenylimines-III. Regioselectivity in Hg(II) cyclometallated complexes, Yangjie Wu, Xiuling Cui, Yuanhong Liu, Hanzhen Yuan, Xian Mao, J. Organomet. Chem., 1997, 543, 63.

Patent

二茂铁咪唑啉环钯化合物、其制备以及在催化合成偶联产物方面的应用, 崔秀灵，马骥，吴养洁， 2009，专利号：200710053932.2高分子固载钯络合物作为高效、无磷、稳定、可循环催化剂催化Heck反应，2004，林昆华，宋毛平，吴养洁，崔秀灵，专利号: 02139082.7.

词条	崔秀玲
释义	宁波市人大常委会副主任郑州大学化学系研究生导师(Dr. Xiuling Cui Research interest Education and Training Main Award Selected Publication Patent) 宁波市人大常委会副主任崔秀玲，女，汉族，浙江鄞县人，1958年9月出生，本科学历，1981年8月参加工作。历任宁波市鄞县林业局副局长、鄞县人民政府县长助理、副县长、鄞州区人民政府副区长。现任宁波市人大常委会副主任。郑州大学化学系研究生导师 Dr. Xiuling Cui Full Professor, Chemistry Department, Zhengzhou University, 2008 Associate Professor, Chemistry Department, Zhengzhou University, 2002 Research interest The research in our group on Organometallic Chemistry combines techniques of organic synthesis, physical organic chemistry and organometallic chemistry. In recent years, C-C, C-N and C-O bond-forming processes have become among the most important reactions in the pharmaceutical and fine chemical industry. So we have been interested in the development of optimized catalytic processes, green catalyst and solvents to accomplish this important task. Our research involves the synthesis of metal complexes; development of environmentally catalytic processes; study on the novel chiral ligands for asymmetric synthesis; investigation on the kindly environmental catalytic system for important medicine intermediates. Education and Training Postdoctoral Research Associate: 09/2000-08/2006 Instituto de Tecnologia Quimica e Biologica, University Nova de Lisboa, Portugalwith Postdoctoral fellowship grand from Portuguese Ministry of Scientific and Technological with Professor Rita Delgado Preparation and study of new molecules working as redox sensor for transition metal ions, bio-anions or bio-neutral molecules Ph. D.: (09/1996-07/1999) Department of Chemistry, Zhengzhou University, P. R. China Supervisor: Professor, Academician, Yangjie Wu Study on the cyclometallation of ferrocenylimines and relative stereochemistry aspect M. Sc (09/1993-07/1996) Department of Chemistry, Zhengzhou University, P. R. China Supervisor: Professor, Academician, Yangjie Wu Study on the cyclometallation of ferrocenylimines B. S. (09/89-07/93) Department of Chemistry, Zhengzhou University, P. R. China Teaching: Organic Chemistry, Organic Synthesis Experiment, Chemistry Specialty English Research grant Studies on the synthesis and application of chiral Aza-ferrocenophanes (手性氮杂二茂铁环番的合成及其应用研究, 国家自然科学资金20972139) Studies on the palladacycles catalyzed C-C, C-heteratom bond forming and its mechanism （环钯化合物催化碳-碳、碳-杂原子键的生成及其机理研究，河南省自然科学资金082300423201) Main Award 2004 Application of Cyclopalladated Complexes in Organic Synthesis, Research Fund award from Chinese National Personal Ministry 2003 Application of Cyclometallated Complexes in Organic Synthesis, Research Fund award from Chinese National Education Ministry 2002 Project: Cyclometallation Reaction and Intramolecular Coordination First-class award in advanced scientific and technological research warded by Henan Provincial government P.R. China 2001 Excellent Young Professor in Universities in Henan province 2000 to 2006 Postdoc. Grant from Portuguese Ministry of Scientific and Technological Selected Publication Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C-H Activation under External-Oxidant-Free Conditions，Junliang Wu, Xiuling Cui,* Lianmei Chen, Guojie Jiang, Yangjie Wu* J. Am. Chem. Soc,2009, 13888-13889Synthesis and Structure of Heteroannular Cyclopalladated Chiral Ferrocenylimines. Theoretical Interpretation of the Cyclopalladated Complexes Based on Density Functional Calculations Hengyu Qian,Xiuling Cui, Mingsheng Tang, Chun Hui, Cheng Liu, Yangjie Wu, New J. Chem2009，33，668-674Ferrocenylimidazoline Palladacycles as Efficient Catalysts for the Aza-Claisen Rearrangement Reaction of Allylic Imidates，Ji Ma, Xiuling Cui, Dejian Yang, Junliang Wu,Maoping Song, Yangjie Wu，App. Organomet. Chem., 2008, 624-628Ferrocenylimidazoline palladacycles: efficient phosphine-free catalysts for suzuki-miyaura cross-coupling reaction，Ji Ma, Xiuling Cui, Bi Zhang, Maoping Song, Yangjie Wu，Tetrahedron,2007, 2007, 63(25) 5529-5538Cyclopalladated ferrocenylimines: efficient catalysts for homocoupling and sonogashira reaction of terminal alicynes, Fan Yang, Xiuling Cui, Yanan Li, Jinli Zhang, Gerui Ren and Yangjie Wu, Tetrahedron, 2007, 63, 1963-1969Ferrocenyl-imidazoline palladacycles: syntheses, crystal structures and applications as Suzuki cross coupling catalysts in water, Ji Ma, Xiuling Cui, Liuyi Gao, Yangjie Wu, Inorg. Chem. Commou.*2007, 10(7), 762-766.Carboxylate anions recognition and sensing by novel receptor--- ferrocene functionalized polyamine, Xiuling Cui, Rita Delgado, Michael G. B. Drew, and Vitor Felix,Dalton Trans. 2005, 3297-3306Bis[1,1'-N,N'-(2-picolyl)aminomethyl]ferrocene as a Redox Sensor for Transition Metal Ions，Xiuling Cui, Helena Carapura, Rita Delgado，Michael G. B. Drew and Vítor Félix，DaltonTrans., 2004, 1743-1751.Complexation properties of a tetraazamacrocycle with phenol pendant arms: X-ray structures, spectroscopic and DFT studies, Xiuling Cui, Maria José Calhorda, Paulo J. Costa, Rita Delgado, Michael G. B. Drew and Vítor Félix，Helev. Chim. Acta., 2004, 2613-2628.Synthesis of Novel Chiral Tellurium Complexes by Redox Reaction of Planar Chiral Cyclomercurated Ferrocenylimines with Tellurium Powder and X-ray Crystal Structure of TeCl{C5H5FeC5H3C(CH3)=N-C6H4-4-CH3} Yangjie Wu, Liangru Yang, Xiuling Cui, Chenxia Du, Yu Zhu, Tetrahedron: Asymmetry, 2003, 14(8), 1073-1077. Invited Review: Studies on the cyclometallation of ferrocenylimines, Yangjie Wu, Shouquan Huo, Junfang Gong, Xiuling Cui, Li Ding, Kuiling Ding, Chenxia Du, Yuanhong Liu and Maoping Song, J. Organomet. Chem., 2001, 637-639, 27-46。Synthesis, isolation and structural characterization of optically active planar chiral cyclomercurated ferrocerylimines, Yangjie Wu, Xiuling Cui, Ning Zhou, Maoping Song, Hongying Yun, Chenxia Du, Yu Zhu, Tetrahedron: Asymmetry, 2000, 11, 4877.Transmetallation Reactions of Planar Chiral Cyclopalladated and Cyclomer-curated Ferrocenylimines with Metallic Tin, Yangjie Wu, Xiuling Cui, Jianjun Hou, Liangru Yang, Min Wang, Acta. Chim. Sinica, 2000, 58(7), 871. （For Academician Youqi Tang’s 80th birthday）Transmetallation reaction of planar chiral cyclopalladated ferrocenylimines with metallic mercury, Xiuling Cui, Yangjie Wu, Liangru Yang, Tetrahedron: Asymmetry, 1999, 10(7), 1255. Resolution of cyclopalladated ferrocenylketimines, Yangjie Wu, Xiuling Cui, Chenxia Du, Wenling Wang, Ruiyun Guo, Rongfeng Chen, J. Chem. Soc., Dalton Trans.,1998, 22, 3727. Cyclometallation of Ferrocenylimines-III. Regioselectivity in Hg(II) cyclometallated complexes, Yangjie Wu, Xiuling Cui, Yuanhong Liu, Hanzhen Yuan, Xian Mao, J. Organomet. Chem., 1997, 543, 63. Patent 二茂铁咪唑啉环钯化合物、其制备以及在催化合成偶联产物方面的应用, 崔秀灵，马骥，吴养洁， 2009，专利号：200710053932.2高分子固载钯络合物作为高效、无磷、稳定、可循环催化剂催化Heck反应，2004，林昆华，宋毛平，吴养洁，崔秀灵，专利号: 02139082.7.
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