人物简介

个人学位

研究方向

成就及荣誉

学术成果

人物简介

石高全 （教授，理学博士），教育部长江特聘教授

个人学位

1981-1985，南京大学化学系，理学学士

1985-1988，南京大学化学系，理学硕士

1988-1990，南京大学化学系，南京大学化学系博士生

1990-1992，日本国东京农工业大学工学部留学（做博士论文）

1992回国，南京大学化学系，理学博士

1992-1993，南京大学化学系讲师

1993-1995，南京大学化学系副教授

1995-2000，南京大学化学系教授

2000-至今，清华大学化学系教授

研究方向

石墨烯的合成，功能化与应用研究

导电高分子微/纳米结构及其器件的研究

成就及荣誉

本实验室长期以来一直从事导电高分子材料和纳米碳材料的研究。研制了一系列高强度导电高分子材料，特别是电化学合成了强度超过金属铝的聚噻吩膜和力学性能优异的聚苯膜材料。探索了制备各种导电高分子膜材料以及导电高分子/导电纤维复合材料的新方法。利用固体模板和无模板方法制备了高度取向的导电高分子微米/纳米管和导电高分子微容器。对微型容器进行线形组装，并研究了其在生物传感器方面的应用。研制了驱动力强、响应速度快、寿命长的基于导电高分子的驱动器件，并开发了其在抓取生物细胞、微米/纳米粒子方面的应用。 研究了基于导电高分子的各种干性粘附材料用于显示各种材料与物件的干性缝合，平面显示屏以及各种电子元件的悬挂与固定。近年来在石墨烯的化学合成与功能化等方面从事了系列研究工作， 特别是在石墨烯增强高分子复合材料，石墨烯修饰电极以及共轭分子修饰石墨烯等方面取得了进展。 至今发表SCI论文220余篇。一些论文发表在Science, J. Am. Chem. Soc., Chem. Soc. Rev.,等国际一流刊物上。论文被他人引用2600余次。获得过清华大学“清华之友优秀教师”奖。2002年获得国家自然科学基金杰出青年基金资助。2004年获得中国化学会-巴斯夫“青年知识创新奖”。2004年获得国家自然科学基金二等奖（第二获奖人）。2005年获得国务院政府特殊津贴。每年招收博士生1-2名，硕士生1-2名。

学术成果

发表研究论著：

2011 (April)

1. Xu, Y.X. and Shi, G.Q., Assembly of chemically modified graphene: methods and applications. Journal of Materials Chemistry, 2011. 21(10): 3311-3323.

2. Li, Y., Hu, Y., Zhao, Y., Shi, G.Q., Deng, L.E., Hou, Y.B., and Qu, L.T., An Electrochemical Avenue to Green-Luminescent Graphene Quantum Dots as Potential Electron-Acceptors for Photovoltaics. Advanced Materials, 2011. 23(6): 776.

3. Sheng, K. X., Xu, Y. X., Li, C., Shi, G. Q., High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide, New Carbon Materials, 2011, 26(1):9-15.

4. Bai, H; Li, C; Shi, GQ, Functional Composite Materials Based on Chemically Converted Graphene, Advanced Materials, 2011, 23 (9) 1089-1115.

5. Xie, X. J., Bai, H., Shi, G. Q.; Qu, L. T., Load-tolerant, highly strain-responsive graphene sheets, Journal of Materials Chemistry, 2011, 21(7): 2057-2059.

6. Sun, Y. Q., Wu, Q. Shi, G. Q., Graphene based new energy materials, Energy Environ. Sci., 2011, 4, 1113–1132.

2010

1. Xu, Y.X., Wu, Q., Sun, Y.Q., Bai, H., and Shi, G.Q., Three-Dimensional Self-Assembly of Graphene Oxide and DNA into Multifunctional Hydrogels. Acs Nano, 2010. 4(12): 7358-7362.

2. Liu, A.R., Li, C., Bai, H., and Shi, G.Q., Electrochemical Deposition of Polypyrrole/Sulfonated Graphene Composite Films. Journal of Physical Chemistry C, 2010. 114(51): 22783-22789.

3. Yao, Z.Y., Bai, H., Li, C., and Shi, G.Q., Analyte-induced aggregation of conjugated polyelectrolytes: role of the charged moieties and its sensing application. Chemical Communications, 2010. 46(28): 5094-5096.

4. Yao, Z.Y., Li, Y.G., Li, C., and Shi, G.Q., Disassembly of conjugated polyelectrolyte aggregates and their application for colorimetric detection of surfactants in water. Chemical Communications, 2010. 46(45): 8639-8641.

5. Wang, X.L., Bai, H., Yao, Z.Y., Liu, A.R., and Shi, G.Q., Electrically conductive and mechanically strong biomimetic chitosan/reduced graphene oxide composite films. Journal of Materials Chemistry, 2010. 20(41): 9032-9036.

6. Zhao, Y., Hu, Y., Li, Y., Zhang, H., Zhang, S.W., Qu, L.T., Shi, G.Q., and Dai, L.M., Super-long aligned TiO2/carbon nanotube arrays. Nanotechnology, 2010. 21(50).

7. Xie, X.J., Qu, L.T., Zhou, C., Li, Y., Zhu, J., Bai, H., Shi, G.Q., and Dai, L.M., An Asymmetrically Surface-Modified Graphene Film Electrochemical Actuator. Acs Nano, 2010. 4(10): 6050-6054.

8. Li, Y., Zhou, C., Xie, X.J., Shi, G.Q., and Qu, L.T., Spontaneous, catalyst-free formation of nitrogen-doped graphitic carbon nanocages. Carbon, 2010. 48(14): 4190-4196.

9. Bai, H., Li, C., Wang, X.L., and Shi, G.Q., A pH-sensitive graphene oxide composite hydrogel. Chemical Communications, 2010. 46(14):2376-2378.

10. Gao, Y.W., Bai, H., and Shi, G.Q., Electrosynthesis of oligo(methoxyl pyrene) for turn-on fluorescence detection of volatile aromatic compounds. Journal of Materials Chemistry, 2010. 20(15):2993-2998.

11. Hong, W.J., Bai, H., Xu, Y.X., Yao, Z.Y., Gu, Z.Z., and Shi, G.Q., Preparation of Gold Nanoparticle/Graphene Composites with Controlled Weight Contents and Their Application in Biosensors.Journal of Physical Chemistry C, 2010. 114(4):1822-1826.

12. Xu, Y.X., Sheng, K.X., Li, C, Shi, G.Q. Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process ACS Nano 2010, 4(7): 4324-4330.

13. Sheng, K.X., Shi, G.Q., Synthesis of discus-like Poly(3,4-ethylenedioxythiophene) nanoparticles using a bicellar templateSynthetic Metals, 2010, 160(11-12): 1354-1358.

14. Sun, YQ; Li, C; Xu, YX, Bai, H, Yao ZY, Shi GQ, Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst Chemical Communications, 2010, 46(26) :4740-4742.

15. Wu, Q; Xu, YX; Yao, ZY, Liu AR, Shi GQ, Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films.ACS Nano, 2010, 4(4): 1963-1970.

2009

1. Liu, A.R., Zhao, L., Bai, H., Zhao, H.X., Xing, X.H., and Shi, G.Q., Polypyrrole Actuator with a Bioadhesive Surface for Accumulating Bacteria from Physiological Media. Acs Applied Materials & Interfaces, 2009. 1(4):951-955.

2. Chen, Y.Q., Bai, H., Hong, W.J., and Shi, G.Q., Fluorescence detection of mercury ions in aqueous media with the complex of a cationic oligopyrene derivative and oligothymine. Analyst, 2009. 134(10):2081-2086.

3. Xu, Y.X., Hong, W.J., Bai, H., Li, C., and Shi, G.Q., Strong and ductile poly(vinyl alcohol)/graphene oxide composite films with a layered structure. Carbon, 2009. 47(15):3538-3543.

4. Bai, H., Xu, Y.X., Zhao, L., Li, C., and Shi, G.Q., Non-covalent functionalization of graphene sheets by sulfonated polyaniline. Chemical Communications, 2009(13):1667-1669.

5. Yao, Z.Y., Feng, X.L., Hong, W.J., Li, C., and Shi, G.Q., A simple approach for the discrimination of nucleotides based on a water-soluble polythiophene derivative. Chemical Communications, 2009(31):4696-4698.

6. Yao, Z.Y., Feng, X.L., Li, C., and Shi, G.Q., Conjugated polyelectrolyte as a colorimetric and fluorescent probe for the detection of glutathione. Chemical Communications, 2009(39):5886-5888.

7. Li, C., Bai, H., and Shi, G.Q., Conducting polymer nanomaterials: electrosynthesis and applications. Chemical Society Reviews, 2009. 38(8):2397-2409.

8. Feng, X.L., Yao, Z.Y., Li, C., and Shi, G.Q., Self-assembly of insulated molecular wires of a water-soluble cationic PPV and anionic dendrons. Chinese Science Bulletin, 2009. 54(14):2451-2456.

9. Zhao, L., Xu, Y.X., Qiu, T.F., Zhi, L.J., and Shi, G.Q., Polyaniline electrochromic devices with transparent graphene electrodes. Electrochimica Acta, 2009. 55(2):491-497.

10. Zhao, L., Tong, L., Li, C., Gu, Z.Z., and Shi, G.Q., Polypyrrole actuators with inverse opal structures. Journal of Materials Chemistry, 2009. 19(11):1653-1658.

11. Tong, L., Li, C., Chen, F.E., Bai, H., Zhao, L., and Shi, G.Q., Flexible Sandwich Photodetectors Based on Thick Polythiophene Films. Journal of Physical Chemistry C, 2009. 113(17):7411-7415.

12. Xu, Y.X., Zhao, L., Bai, H., Hong, W.J., Li, C., and Shi, G.Q., Chemically Converted Graphene Induced Molecular Flattening of 5,10,15,20-Tetrakis(1-methyl-4-pyridinio)porphyrin and Its Application for Optical Detection of Cadmium(II) Ions. Journal of the American Chemical Society, 2009. 131(37):13490-13497.

13. Chapman, G.M., Bai, H., Li, C., and Shi, G.Q., Micro-nanoscale binary structured silver films fabricated by electrochemical deposition. Materials Chemistry and Physics, 2009. 114(1):120-124.

14. Bai, H., Zhao, L., Lu, C.H., Li, C., and Shi, G.Q., Composite nanofibers of conducting polymers and hydrophobic insulating polymers: Preparation and sensing applications. Polymer, 2009. 50(14):3292-3301.

15. Chen, Y.Q. and Shi, G.Q., Fluorescence Detection and Discrimination of ss- and ds-DNA with a Water Soluble Oligopyrene Derivative. Sensors, 2009. 9(6):4164-4177.

16. Chen, Y.Q., Bai, H., Chen, Q., Li, C., and Shi, G.Q., A water-soluble cationic oligopyrene derivative: Spectroscopic studies and sensing applications. Sensors and Actuators B-Chemical, 2009. 138(2):563-571.

2008

1. Lu, G.W., Hong, W.J., Tong, L., Bai, H., Wei, Y., and Shi, G.Q., Drying Enhanced Adhesion of Polythiophene Nanotubule Arrays on Smooth Surfaces. Acs Nano, 2008. 2(11):2342-2348.

2. Bai, H., Li, C., and Shi, G.Q., Pyrenyl excimers induced by the crystallization of POSS moieties: Spectroscopic studies and sensing applications. Chemphyschem, 2008. 9(13):1908-1913.

3. Hong, W.J., Xu, Y.X., Lu, G.W., Li, C., and Shi, G.Q., Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells. Electrochemistry Communications, 2008. 10(10):1555-1558.

4. Bai, H., Li, C., and Shi, G.Q., Electrochemical Fabrication of Superhydrophobic Surfaces on Metal and Semiconductor Substrates. Journal of Adhesion Science and Technology, 2008. 22(15):1819-1839.

5. Xu, Y.X., Bai, H., Lu, G.W., Li, C., and Shi, G.Q., Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. Journal of the American Chemical Society, 2008. 130(18):5856-+.

6. Ma, T., Li, C., and Shi, G., Optically Active Supramolecular Complex Formed by Ionic Self-Assembly of Cationic Perylenediimide Derivative and Adenosine Triphosphate. Langmuir, 2008. 24(1):43-48.

7. Ma, T., Li, C., and Shi, G.Q., Optically active supramolecular complex formed by ionic self-assembly of cationic perylenediimide derivative and adenosine triphosphate. Langmuir, 2008. 24(1):43-48.

8. Yao, Z.Y., Li, C., and Shi, G.Q., Optically Active Supramolecular Complexes of Water-Soluble Achiral Polythiophenes and Folic Acid: Spectroscopic Studies and Sensing Applications. Langmuir, 2008. 24(22):12829-12835.

9. Zhao, L., Ma, T., Bai, H., Lu, G.W., Li, C., and Shi, G.Q., Layer-by-layer deposited multilayer films of oligo(pyrenebutyric acid) and a perylene diimide derivative: Structure and photovoltaic properties. Langmuir, 2008. 24(8):4380-4387.

10. Bai, H., Li, C., and Shi, G.Q., Rapid nitroaromatic compounds sensing based on oligopyrene. Sensors and Actuators B-Chemical, 2008. 130(2):777-782.

11. Wang, S.B., Li, C., and Shi, G.Q., Photoresponsive properties of multilayers of conductive polymer and CdSe nanoparticles. Solar Energy Materials and Solar Cells, 2008. 92(5):543-549.

12. Li, M., Yuan, J.Y., and Shi, G.Q., Electrochemical fabrication of nanoporous polypyrrole thin films. Thin Solid Films, 2008. 516(12):3836-3840.