个人简历

研究方向

文章及专著

男，中国科学技术大学教授

个人简历

1995.9-1999.7 吉林大学化学系,学士

2000.9-2005.7 中国科学院上海有机化学研究所,博士

2005.11-2008.3 日本京都大学化学系,博士后

2008.4-2011,3 美国Scripps研究所,研究助理

2011,3-至今 中国科学技术大学化学系,教授

研究方向

1.过渡金属催化的碳-氟(含氟官能团)键形成反应;

2.过渡金属催化的惰性键活化;

3.过渡金属或有机小分子催化的含氟有机化合物的不对称合成;

4.过渡金属催化的新型反应的探索及其在天然产物合成中的应用.

文章及专著

1. Wang, X.; Leow, D.; Yu, J.-Q. “Pd(II)-Catalyzed Para-Selective C?H Arylation of Mono-substituted Arenes” J. Am. Chem. Soc. 2011, in revision.

2. Chan, K. S. L.; Wasa, M.; Wang, X.; Yu, J.-Q. “Palladium(II)-Catalyzed Selective Monofluorination of Benzoic Acids Using a Practical Auxiliary: A Weak-Coordination Approach” Angew. Chem., Int. Ed. 2011, Early View.

3. Engle, K. E.; Mei, T.-S.; Wang, X.; Yu, J.-Q. “Bystanding F+ oxidants for selective reductive elimination from high-valent metal centers in catalysis” Angew. Chem., Int. Ed. 2011, 50, 1078-1091.

4. Wang, X.; Lu, Y.; Dai, H.-X.; Yu, J.-Q. “Pd(II)-catalyzed hydroxyl-directed C?H activation/C?O cyclization: expedient construction of dihydrobenzofurans” J. Am. Chem. Soc. 2010, 132, 12203-12205.

5. Wang, X.; Truesdale, L.; Yu, J.-Q. “Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter” J. Am. Chem. Soc. 2010, 132, 3648-3649.

6. Wang, X.; Lan, Q.; Shirakawa, S.; Maruoka, K. “Chiral bifunctional phase transfer catalysts for asymmetric fluorination of ?-keto esters” Chem. Commun. 2010, 46, 321-323.

7. Mei, T.-S.; Wang, X.; Yu, J.-Q. “Pd(II)-catalyzed amination of C?H bonds using single-electron or two-electron oxidants” J. Am. Chem. Soc. 2009, 131, 10806-10807.

8. Wang, X.; Mei, T.-S.; Yu, J.-Q. “Versatile Pd(OTf)2?2H2O-catalyzed ortho-fluorination using NMP as a promoter” J. Am. Chem. Soc. 2009, 131, 7520-7521.

9. He, R.; Wang, X.; Hashimoto, T.; Maruoka, K. “Binaphthyl-modiried quaternary phosphonium salts as chiral phase-transfer catalysts: asymmetric amination of ?-Keto Esters” Angew. Chem., Int. Ed. 2008, 47, 9466-9468.

10. Wang, X.; Kitamura, M.; Maruoka, K. “New, chiral phase transfer catalysts for effecting asymmetric conjugate additions of ?-alkyl-?-cyanoacetates to acetylenic esters” J. Am. Chem. Soc. 2007, 129, 1038-1039.

11. Wang, X.; Ding, K. “One-pot enantioselective aziridination of olefins catalyzed by a copper(I) complex of a novel diimine ligand by using PhI(OAc)2 and sulfonamide as nitrene precursors” Chem.?Eur. J. 2006, 12, 4568-4575.

12. Wang, X.; Wang, X.; Guo, H.; Ding, K. “Self-supported heterogeneous titanium catalysts for enantioselective carbonyl-ene and sulfoxidation reactions” Chem.?Eur. J. 2005, 11, 4078-4088.