词条 | 童明良 |
释义 | 童明良1967年7月出生,毕业于中山大学化学与化学工程学院, 现为中山大学化学学院教授 ,科研项目有十几种,如水热条件下的有机配体反应及其应用、稀土配合物发光材料的分子设计及应用等, 论著五十多部。 基本信息姓名:童明良 (TONG Ming-Liang) 籍贯:湖北省黄冈市罗田县 出生年月:1967年7月18日 工作单位:中山大学化学与化学工程学院无机化学与材料研究所 职 位:无机化学、材料化学与物理 教授,博士生导师 主要学历1985.9-1989.6:华中师范大学化学系 大学本科 1993.9-1996.6:中山大学化学系 硕士研究生 1996.9-1999.6:中山大学化学与化学工程学院 博士研究生 主要经历1999.1-1999.6:香港中文大学化学系 短期访问学者 2001.11-2003.8:日本京都大学 JSPS博士后特别研究员 1999.7-2004.4:中山大学化学学院 讲师、副教授 2004.5-至今:中山大学化学学院 教授 2003.11-至今:中山大学化学学院 材料物理与化学专业博士生导师 2006.11-至今:中山大学化学学院 无机化学(跨)专业博士生导师 2001.1-至今:光电材料与技术国家重点实验室 固定研究人员 2006.1-至今:生物无机与合成化学教育部重点实验室 固定研究人员 讲授课程本科生:《普通化学》、《无机化学》、《无机化学实验》、《文献查阅》、《现代化学》(逸仙班) 研究生:《超分子化学》、《现代化学研究方法和技术》、《化学前沿进展》 科研项目1. 二-四连接体配位导向的功能配位高分子的构筑与拓扑学研究,国家自然科学基金(No. 20471069),25万, 负责人, 2005.1-2007.12 2. 氧心金属簇合物超分子的组装及结构与性质,国家自然科学基金(No. 20001008),22万,负责人,2001.1-2003.12 3. 簇(配)合物与簇基配位聚合物,高等学校全国优秀博士学位论文作者专项资金(No. 200122),65万,负责人,2002.1-2006.12 4. 具有纳米尺寸的多核簇(配)合物的分子设计、合成与性质, 教育部优秀青年教师资助计划, 8万, 负责人, 2004.1-2006.12 5. 功能簇(配)合物的合成、结构及光电磁性质, 广东省教育厅“千百十工程”优秀人才培养基金),5万,负责人,2002.1-2003.12 6. 氧心金属簇(配)合物的合成、结构与性质研究,结构化学国家重点实验室基金项目(No. 010039),3万,负责人,2001.1-2003.12 7. 高核氧合铁锰等簇(配)合物超分子的合成、结构与性质研究,中山大学青年教师启动基金项目,2万,负责人,2000.1-2001.12 8. 无机—有机杂化材料控制合成、结构调控及性质性质,国家自然科学基金重点项目(No. 20131020),120万,第一参加,2002.1-2005.12 9. 无机-有机杂化新材料研究,广东省自然科学基金研究团队项目(04205405),30万/年,5个核心成员之一,2005.1月-2007.12 10. 水热条件下的有机配体反应及其应用,高等学校博士学科点专项科研基金项目(No. 20020558024),5万,第二参加,2003.1-2005.12 11. 稀土配合物发光材料的分子设计及应用,广东省自然科学基金重点项目(No. 036601),15万,第二参加,2004.1-2006.12 12. 含芳香氮氧配体金属有机发光新材料的制备与器件研究,广东省科技厅重大研究专项B,15万,第二参加,2003.11-2005.10 13. 国家重点基础研究发展计划(973计划)“物质性能的分子设计与结构调控”项目子课题:分子基磁性固体的设计与结构调控(2007CB815305),83万,2007.7-2011.8 14. 国家杰出青年科学基金项目 (No. 20525102):功能金属簇合物与微孔型簇基配位聚合物的合成与性能研究,160万,2006.1-2009.12,项目负责人 15. 国家自然科学基金委创新研究群体基金项目(20821001):功能金属配合物的超分子化学与晶体工程,500万,2009.1-2011.12,骨干成员 16. 国家自然科学基金重大研究计划培育项目(No. 90922009):手性簇(聚)合物晶体的设计组装与光磁性质研究,50万,2010.1-2012.12 17. 国家自然科学基金面上项目 (No. 50872157):具有大的自旋基态金属氧簇单分子磁性材料的设计合成与磁性调控,39万,2009.1-2011.12,项目负责人 主要论著(影响因子2.2以上的论文) 1. Tong M.-L.*, Monfort M., Clemente Juan J. M., Chen X.-M., Bu X.-H., Ohba M. and Kitagawa S.*: A novel high-spin heterometallic Ni12K4 cluster incorporating largest Ni-azide circles and an in situ cyanomethylated di-2-pyridyl ketone Chem. Commun., 2004, in press. 2. Zheng Y.-Z., Tong M.-L.*, Chen X.-M.*: Controlled hydrothermal synthesis of copper(II or I,II) coordination polymers via pH-dependent in-situ metal/ligand redox reactions New J. Chem., 2004, 28, in press. 3. Ye B.-H., Tong M.-L. and Chen X.-M.*: Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands Coord. Chem. Rev., 2004, in press. 4. Qin C., Wang X. Carlucci L., Tong M.-L., Wang E.*, Hu C. and Xu L.: From arm-shaped layers to a new type of polythreaded array: a three-dimensional interpenetrating net with rutile topology Chem. Commun., 2004, 1876-1877. 5. Tong M.-L.*, Susumu Kitagawa*, Ho-Chol Chang and Masaaki Ohba: Temperature-controlled hydrothermal synthesis of a 2D ferromagnetic coordination bilayered polymer and a novel 3D network with inorganic Co3(OH)2 ferrimagnetic chains Chem. Commun., 2004, 418-419. 6. Bu X.-H.*, Tong M.-L., Chang H.-C., Kitagawa S.*, and Batten S. R.: A novel neutral three-dimensional copper coordination polymer showing one-dimensional channels and the first interpenetrating NbO-type network Angew Chem. Int. Ed., 2004, 43, 192-195. 7. Tong M.-L.*, Chen X.-M. and Batten S. R.*: A new Self-Penetrating uniform net, (8,4) (or 86), containing 4-coordinate nodes J. Am. Chem. Soc., 2003, 125, 16170-16171. 8. Zheng S.-L., Tong M.-L. and Chen X.-M.*: Silver(I)–hexamethylenetetramine molecular architectures: from self-assembly to designed assembly Coord. Chem. Rev., 2003, 246, 185-202. 9. Tong M.-L.*, Wu Y.-M., Y.-X. Tong, Chen X.-M.* and Kitagawa S.*: Rational design of a ferromagnetic coupled trinuclear copper(II) complex with a novel in-situ synthesized metalloligand Eur. J. Inorg. Chem., 2003, 2385-2388. 10. Tong M.-L.*, Ru J., Wu Y.-M., Chen X.-M.*, Chang H.-C., Mochizuki K. and Kitagawa S.*: Cation templating constructions of three-dimensional ?-Po cubic-type [M(dca)3]- networks. Syntheses, structures and magnetic properties of A[M(dca)3] (dca = dicyanamide; for A = benzyltributylammonium, M = Mn2+, Co2+; for A = benzyltriethylammonium, M = Mn2+, Fe2+) New J. Chem., 2003, 27, 779–782. 11. Zhang X.-M., Tong M.-L., Gong M.-L. and Chen X.-M.*: Supramolecular organisation of polymeric coordination chains into a three-dimensional network with nanosized channels that clathrate large organic molecules Eur. J. Inorg. Chem., 2003, 138-142. 12. Tong M.-L., Li L.-J., Mochizuki K., Chang H.-C., Chen X.-M., Li Y., Kitagawa S.*: A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units Chem. Commun., 2003, 428-429. 13. Tong M.-L.*, Wu Y.-M., Ru J., Chen X.-M.*, H.-C. Chang and Kitagawa S.*: Pseudo-polyrotaxane and ?-sheet layer-based three-dimensional co-ordination polymers constructed with silver salts and flexible pyridyl-type ligands Inorg. Chem., 2002, 41, 4846-4848. 14. Zhang X.-M., Tong M.-L., Gong M.-L., Lee H.-K., Luo L., Li K.-F., Tong Y.-X. Chen X.-M.*: Syntheses, crystal structures and physical properties of dinuclear copper(I) and tetranuclear mixed-valence copper(I,II) complexes with hydroxylated bipyridyl-like ligands Chem. Eur. J. 2002, 8, 3187-3194. 15. Tao J., Zhang Y., Tong M.-L., Chen X.-M.*, Yuen T., Lin C. L., Huang X. and Li J.: A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions Chem. Commun. 2002, 1342-1343. 16. Tong M.-L.*, Lin Z.-J., Li W., Zheng S.-L. and Chen X.-M.*: Metal cation-supported supramolecular crown ethers featuring hydrogen-bonded tetrameric unit of 2-hydroxy pyridines Cryst. Growth & Design, 2002, 2, 443-448. 17. Tong M.-L.*, Shi J.-X. and Chen X.-M.*: Two Novel Photoluminescent Two-Dimensional Coordination Polymers Constructed with Octanuclear Silver(I) Clusters or Silver(I) Ions New J. Chem. 2002, 26, 814-816. 18. Tong M.-L.*, Zheng S.-L., Shi, J.-X., Tong Y.-X., Lee H. K. and Chen X.-M.*: Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form J. Chem. Soc., Dalton Trans., 2002, 1727-1734. 19. Zheng S.-L., Tong M.-L.*, Chen X.-M.*, and Ng S.-W.: Self-assembly of new three-dimensional molecular architectures constructed from silver(I)-hexamethylenetetramine layers with supramolecular interactions J. Chem. Soc., Dalton Trans., 2002, 360-364. 20. Zhang X.-M., Tong M.-L. and Chen X.-M.*: Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence CuI/CuII Complexes Angew. Chem. Int. Ed. 2002, 41, 1029-1031. 21. Tong M.-L.*, Wu Y.-M., Zheng S.-L., Chen X.-M.*, Yuen T., Lin C. L., Huang X., and Li J.*: A three-dimensional honeycomb-like network constructed with novel one-dimensional S-shaped chains via hydrogen bonding and ?-? interactions New J. Chem., 2001, 25, 1482-1485. 22. Zheng S.-L., Tong M.-L.*, Tan S.-D., Wang Y., Shi J.-X., Tong Y.-X., Lee H. K., and Chen X.-M.*: Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dicarboxylates with hexamethylenetetramine exhibiting unique metal?? interaction Organometallics 2001, 20, 5319-5325. 23. Zheng S.-L., Tong M.-L.*, Zhu H.-L. and Chen X.-M.*: Four two-dimensional highly undulated silver(I)-hexamethylenetetramine co-ordination networks containing micropores New J. Chem., 2001, 25, 1425-1429. 24. Tao J., Shi J.-X., Tong M.-L.,* Zhang X.-X. and Chen X.-M.*: A new inorganic-organic photoluminescent material constructed with helical [Zn3(μ3-OH)(μ2-OH)] chains Inorg. Chem. 2001, 40, 6328-6330. 25. Long L.-S., Chen X.-M., Tong M.-L., Sun Z.-G., Ren Y.-P., Huang R.-B. and Zheng L.-S.*: An unique open inorganic-organic framework with alternate hexa- and penta-co-ordinate cobalt(II) sites. Synthesis, crystal structure and magnetic properties of [{Co3(C4H4O4)2.5(OH)}?0.5H2O]n J. Chem. Soc., Dalton Trans. 2001, 2888-2890. 26. Zhang X.-M., Tong M.-L.* and Chen X.-M.*: The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2] J. Chem. Soc., Dalton Trans. 2001, 2069-2070. 27. Zheng S.-L., Tong M.-L.*, Zhu H.-L., Fang Y. and Chen X.-M.*: Syntheses and structures of three two-dimensional silver(I)-hexamethylenetetramine co-ordination polymers with new topological motifs J. Chem. Soc., Dalton Trans., 2001, 2049-2053. 28. Zheng S.-L., Tong M.-L.*, Fu R.-W., Chen X.-M.* and Ng S. W.: Towards designed assembly of microporous coordination networks constructed from the silver(I)-hexamethylenetetramine layers Inorg. Chem., 2001, 40, 3562-3569. 29. Tao J., Zhang X.-M., Tong M.-L.* and Chen X.-M.*: A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4?-bpy)]n2n+ layers and V4O124– pillars J. Chem. Soc., Dalton Trans. 2001, 770-771. 30. Zheng S.-L., Tong M.-L.*, Yu X.-L. and Chen X.-M.*: Syntheses and structures of six chain-, ladder- and grid-like co-ordination polymers constructed from ?2-hexamethylenetetramine and silver salts J. Chem. Soc., Dalton Trans., 2001, 586-592. 31. Tao J., Tong M.-L.* and Chen X.-M.*: Hydrothermal synthesis and crystal structures of three-dimensional coordination frameworks constructed with mixed N- and O-donor ligands: [M(tp)(4.4’-bipy)] (M=Co(II), Cd(II) and Zn(II); tp = terephthalate; 4,4’-bipy = 4,4’-bipyridine) J. Chem. Soc., Dalton Trans., 2000, 3669-3674. 32. Tao J., Tong M.-L., Shi J.-X., Chen X.-M.* and Ng S. W.: Blue photo-luminescient zinc coordination polymers with supertetranuclear cores J. Chem. Soc., Chem. Commun., 2000, 2043-2044. 33. Tong M.-L., Lee, H. K., Tong Y.-X., Chen X.-M.* and Mak T. C. W.: An octanuclear copper(II) complex containing the gem-diol anionic form of di-2-pyridyl ketone (dpd-2H) and 2-hydroxylpyridine [2-(OH)C5H4N]. Synthesis, crystal structure and properties of [Cu8(dpd-2H)4(?2-O2CMe)4{2-(OH)C5H4N}4](ClO4)4?4H2O Inorg. Chem., 2000, 39, 4666-4669. 34. Tong M.-L., Zheng S.-L. and Chen X.-M.*: Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different silver(I) salts Chem. Eur. J., 2000, 6, 3729-3738. 35. Zhang X.-M., Tong M.-L. and Chen X.-M.*: Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [?Co(phen)2?2V6O17]n and [?Cu(phen)2?4V10O29]?6H2O J. Chem. Soc., Chem. Commun., 2000, 1817-1818. 36. Tong M.-L., Chen H.-J. and Chen X.-M.*: Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4’-bpy)3(H2O)2(phba)2](NO3)2?4H2O (M = Cu2+ or Co2+ ; 4,4’-bpy = 4,4’-bipyridine; phba = 4-hydroxybenzoate) Inorg. Chem., 2000, 39, 2235-2238. 37. Tong M.-L. and Chen X.-M.*: Anionic and neutral metal-4,4’-bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4’-bipyridine CrystEngComm, 2000, 2(1), 1-5. 38. Tong M.-L., Lee H. K.*, Chen X.-M.*, Huang R.-B. and Mak T. C. W.: A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4’-bipyridine)2(H2O)4]2+ cations and rich solvate 4,4’-bipyridine molecules through hydrogen-bonding and ??? interactions J. Chem. Soc., Dalton Trans., 1999, 3657-3659. 39. Tong M.-L., Zheng S.-L. and Chen X.-M.*: Two- and three-dimensional non-interpenetrating open-networks self-assembled by ?4-hexamethylenetetramine (hmt). Syntheses and structures of [Ag2(?4-hmt)(SO4)(H2O)]?4H2O and [Ag2(?4-hmt)(?2-O2CMe)](MeCO2)?4.5H2O J. Chem. Soc., Chem. Commun., 1999, 561-562. 40. Tong M.-L., Chen X.-M.*, Ye B.-H. and Ji L.-N.: Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds. Syntheses, structures and luminescent properties Angew. Chem. Int. Ed., 1999, 38, 2237-2240. 41. Tong M.-L., Chen X.-M.*, Ye B.-H. and Ng S. W.: Helical silver(I)-2,4’-bipyridine chains organized into 2-D networks by metal-counterion or metal-metal bonding. Structures of [Ag(2,4’-bipyridine)]X (X- = NO3- or ClO4-) Inorg. Chem., 1998, 37, 5278-5281. 42. Tong M.-L., Ye B.-H., Cai J.-W., Chen X.-M.* and Ng S. W.: Clathration of Two-Dimensional Coordination Polymers: Syntheses and Structures of [M(4,4’-bpy)2(H2O)2](ClO4)2?(2,4’-bpy)2?H2O and [Cu(4,4’-bpy)2(H2O)2](ClO4)4 ?(4,4’-H2bpy) (M = CdII, ZnII and bpy = bipyridine) Inorg. Chem., 1998, 37, 2645-2650. 43. Tong M.-L., Chen X.-M.*, Yu X.-L. and Mak T. C. W.: A novel two-dimensional rectangular network. synthesis and structure of {[Cu(4,4’-bpy)(pyz)(H2O)2](PF6)2}n (bpy = bipyridine, pyz = pyrazine) J. Chem. Soc., Dalton Trans., 1998, 5-6. 44. Chen X.-M.*, Tong M.-L., Wu Y.-L. and Luo Y.-J.: Synthesis and structure of a novel carboxylate-bridged heterometallic copper(II)-gadolinium(III) complex J. Chem. Soc., Dalton Trans., 1996, 2181-2182. |
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