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词条 邱化玉
释义

杭州师范大学教授

男,1963年5月生于山东,中共党员,理学博士,教授,博士研究生导师,享受国务院政府特殊津贴,浙江省高等学校特聘教授(钱江学者)、浙江省“151”人才第一层次、山东省千名知名技术专家。美国科学促进会会员、美国化学会会员、中国化学会会员。1984年毕业于山东大学化学系,获理学学士学位,同年考取山东大学化学系高分子专业硕士研究生,师从于著名有机硅专家杜作栋教授,1987年获理学硕士学位并留在山东大学新材料研究所工作;1992年考取山东大学化学学院物理化学专业的博士研究生,师从于中国科学院院士、著名理论化学家邓丛豪教授,1996年获理学博士学位,同年赴美国北达克他州立大学化学系做博士后研究工作。2005年2月受聘杭州师范大学有机硅化学及材料技术教育部重点实验室教授,现担任材料与化学化工学院院长。1994年10月破格晋升副教授,1998年11月破格晋升教授。曾获山东省科技进步一等奖和二等奖、山东省教育厅理论成果一等奖等多项奖励。已公开发表学术论文150余篇,有100多篇被SCI、EI和ISTP收入。主持和参与国家“八五”、“九五”科技攻关计划、国家自然科学基金、山东省中青年科学家奖励基金、山东省自然科学基金、浙江省科技计划重点项目、杭州市科技计划重点项目等20多项科研课题的研究工作。主要研究方向为高分子化学及高分子化学、有机硅化学和有机硅材料。

获奖情况:

1.新型有机硅化合物和聚合物的研究, 山东省自然科学一等奖,1991年

2.有机硅微乳液皮革手感剂的研究,山东省科技进步二等奖,2004年

3.新型聚硅烷的研究,获山东省教育厅科技进步理论成果一等奖,1991年

4.浙江省高等学校特聘教授(钱江学者),2005年

5.浙江省“151”人才第一层次,2006年

6.山东省千名知名技术专家,2003年

近年发表的主要论文:

1. Xu, Z.; Jin, J.; Li, Z.-F.; Qiu, H.-Y.(邱化玉); Jiang, J.-X.; Lai, G.-Q.; Kira, M. Remarkable Substituent Effects on the Activation Energy of Silylene Insertion into Silicon–Chlorine Bonds.Chem. Eur. J. 2009, 15, 8605-8612. (IF:5.454

2. Yang, C.-J.; Chen, X.*; Qiu, H.-Y. * (邱化玉); Zhuang, W.-C.; Chai, Y.-C.; Hao, J.-C. Dissipative particle dynamics simulation of phase behavior of aerosol OT/water system.J. Phys. Chem. B 2006, 110, 21735–21740. (IF:4.189

3. Wan, J.-H.; Fang, W.-F; Li, Z.-F.; Xiao, X.-Q.; Xu, Z.; Deng; Y., Zhang, L.-H.,;Jiang, J.-X.; Qiu, H.-Y. (邱化玉); Wu, L-B.; Lai, G.-Q.*Novel Ladder π-Conjugated Materials—Sila-Pentathienoacenes: Synthesis, Structure, and Electronic Properties. Chem. Asian J. 2010,5,2290-2296. (IF:4.197

4. Wan, J.-H.;Mao, L-Y.; Li, Y.-B.; Li, Z.-F.; Qiu, H.-Y. (邱化玉); Wang,C.; Lai, G.-Q.* Self-assembly of novel fluorescent silole derivatives into different supramolecular aggregates: fibre, liquid crystal and monolayer. Soft Matter.2010,6,3195-3201. (IF:4.586

5. Jin, S.-W, Chen, W.Z*, and Qiu, H.-Y.*(邱化玉) Syntheses and Structural Characterization of a One-Dimensional Chain, Two-Dimensional Noninterpenetrated Grid, and Three-Dimensional Polycatenane Coordination Polymers Assembled from Flexible Bidentate Imidazolyl Ligands. Cryst. Growth Des. 2007,7,2071-2079. (IF:4.04

6. Lu, C.-X.; Gu, S.-J.; Chen, W.-Z.*; Qiu, H.-Y.*(邱化玉) Platinum(II) complexes with polydentate N-heterocyclic carbenes: synthesis,structural characterization and hydrosilylation catalysis. DaltonTrans. 2010, 39, 4198–4204. (IF:3.58

7. Lai, G.-Q.; Xu, Z.; Li, Z.-F.; Jiang, J.-X.; Kira, M.*; Qiu, H.-Y. * (邱化玉) Stereoelectronic substituent effects on silylene insertion into the Si-Cl bond. Organometallics 2009, 28, 3591–3593(IF:3.815

8. Jing, B.; Chen, X.; Zhao, Y.-R; Wang, X.-D.; Cai, J.-G.; Qiu, H.-Y. (邱化玉) Ionic self-assembled organic nanobelts from the hexagonal phase complexes and their cyclodextrin inclusions. J. Phys. Chem. B 2008, 112, 7191-7195. (IF:4.189

9. Zhang, G.-D; Chen, X.; Zhao, Y.-R; Ma, F.-M.; Jing, B.; Qiu, H.-Y. (邱化玉) Lyotropic liquid-crystalline phases formed by Pluronic P123 in ethylammonium nitrate.J. Phys. Chem. B 2008, 112, 6578-6584. (IF:4.189

10. Zhang, G.-D.;Chen, X.;Zhao, Y.-R.; Xie, Y.-Z .; Qiu, H.-Y. (邱化玉) Effects of alcohols and counterions on the phase behavior of 1-octyl-3-methylimidazolium chloride aqueous solution. J. Phys. Chem. B 2007, 111,11708-11713. (IF:4.189

11. Jing, B.; Chen, X.; Wang, X.-D.; Zhao, Y.-R .; Qiu, H.-Y. (邱化玉) Sol-gel-sol transition of gold nanoparticle-based supramolecular hydrogels induced by cyclodextrin inclusion. ChemPhysChem. 2008,9,249-252. (IF:3.636

12. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Qiu, H.-Y. * (邱化玉); Jiang, K.-Z.; Jiang, J.-X.; Lai, G.-Q.* Ionic liquid (molten salt): Thermoregulated catalyst support for catalytic hydrosilylation process. Catal. Commun. 2008, 9, 2236–2238. (IF:2.791

13. Zhou, Y.-B.; Zhang, X.-M.; Chen, W.-Z.*; Qiu, H.-Y. * (邱化玉) Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem., 2008, 693, 205–215. (IF:1.866

14. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Gao, W.-H.; Qiu, H.-Y. * (邱化玉); Wu, H.; Deng, Y.; Lai, G.-Q.* Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 2007, 278, 97–101. (IF:2.814

15. Li, Z.-F.; Cao, X.-J.; Lai G.-Q.*; Liu, J.-H.; Ni, Y.; Wu, J.-R.; Qiu, H.-Y. * (邱化玉) Controlled introduction of allylic group to chlorosilanes. J. Organometal. Chem. 2006, 691, 4740–4746. (IF:1.866

16. Li, Z.-F. Yang, C.-J. Zheng, H.-F. Qiu, H.-Y. (邱化玉) ;. Lai, G.-Q* Selective mono- and di-allylation and allenylation of chlorosilanes using indium. J. Organometal. Chem. 2008, 693: 3771-3779.

17. Jiang, K.-Z.; Ni, Y.; Qiu, H.-Y. * (邱化玉); Li, M.-J.; Jiang, J.-X.; Lai, G.-Q.* Separation of the isomers of oligomethylphenylcyclosiloxanes and determination of their structures by capillary GC-MS. Chromatographia. 2006, 64, 689–694. (IF:1.312

18. Lai, G.-Q.; Peng, J.-J.; Li, J.-Y.; Qiu, H.-Y. (邱化玉); Jiang, J.-X.; Jiang K.-Z.; Shen, Y.-J.* Ionic liquid functionalized silica gel: novel catalyst and fixed solvent. Tetrahedron Lett. 2006, 47, 6951–6953. (IF:2.538

19. Ju, Y.-D. Xu, L.W.; Li, L.; Lai, G.-Q.*; Qiu, H.-Y. (邱化玉);, Jiang, J.-X.; Lu,Y-X. Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio-and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins. Tetrahedron Lett. 2008,49,6773-6777.(Highlighted by SYNFACTS,2008,1328). (IF:2.538

20. Peng, J.-J.; Li, J.-Y.; Bai, Y.; Gao, W.-H.; Qiu, H.-Y. (邱化玉);,Wu,H.; Deng,Y.; Lai, G.-Q.* Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. J. Mol. Catal. A-Chem. 2007, 278, 97-101. (IF:2.814

21. Xu, L.-W.; Yang, M.-S.; Qiu, H.-Y.* (邱化玉);, Lai, G.-Q.*; Jiang, J.-X. Efficient iron-catalyzed Sakurai-Michael addition of allyltrimethylsilane to chalcones. Synthetic Commun. 2008, 38, 1011-1019. (IF:0.981

22. Yang, M.-S.; Xu, L.-W.; Qiu, H.-Y.* (邱化玉);, Lai, G.-Q.*; Jian;g, J.-X. Highly efficient indium-catalyzed chemo- selective allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes. Tetrahedron. Lett. 2008, 49, 253-256. (IF:2.538

23. Yang, M.-S.; Xu, L.-W.; Zhang, F.-B.; Qiu, H.-Y.* (邱化玉); Jiang, J.-X.; Lai, G.-Q.* Highly efficient iron-catalyzed allylation of aromatic aldehydes with allyltriethoxysilane: one-pot and practical synthesis of homoallyl ethers. Appl. Organomet. Chem. 2008, 22,177-180. (IF:1.27

24. Chen., C.; Qiu, H.-Y.* (邱化玉);Chen, W.-Z.*;Wang, D.-Q. Synthesis, structural characterization, and luminescence properties of multinuclear silver complexes of pyrazole-functionalized NHC ligands containing Ag-Ag and Ag-pi interactions. J. Organometal. Chem., 2008,693, 205- 215. (IF:1.866

近年主持的主要科研项目:

1.低倍MW级聚光型(CPV)并网电站光伏电池用关键材料的研制,国家“863”重点项目(2006AA050203-1),2008.1-2011.12

2.含Silole和亚硅基σ-π共轭聚合物的设计合成、结构与性能,国家自然科学基金(20974031),2010.1-2010.12

3.含Silole和联三吡啶Zn(Ⅱ)单元共轭金属聚合物的设计、合成及性能研究,国家自然科学基金(21074028),2011.1-2013.12

4.有机硅化学若干基础问题的研究,省高校特聘教授(钱江学者)基金(05TP08),2006.1-2008.12

5.高性能有机硅树脂绿色合成技术开发研究,省科技计划重点项目(2007C21G2150010),2007.10-2009.9

6.高性能有机硅材料的研究及产业化,省科技重大专项(2006C11124),2007.6-2009.12

近年已获授权的国家发明专利:

1. 一种细旦或超细旦尼龙纤维及其生产方法,ZL200710069547.7

2. 一种异硫氰酸酯的合成方法,ZL200610048928.2

3. 有机聚硅烷的制备方法,ZL200510061322.8

5. 一种硅氢加成反应担载型双金属催化剂及制备方法,ZL200710068597.3

6. 一种金属卟啉/二氧化硅降解剂的制备方法,ZL200710067240.3

7. 一种采用新型离子液体聚合引发体系制备高分子化合物的方法,ZL200510061318.1

8. 一种3,4'-二氨基二苯醚的制备及分离提纯方法,ZL200610050813.7

9. 超临界状态下的原子转移自由基聚合引发体系,ZL200610172229.9

10.一种反向ATRP引发体系及其在制备高分子化合物的应用,ZL200610048929.7

11. 多官能基硅化合物的制备, ZL200510061321.3

12. 两步法化学提纯甲基苯基二氯硅烷的方法,ZL200510061322.8

13. 一种羟基封端聚甲基苯基硅氧烷的制备方法,ZL200710068595.4

14. 一种侧链含四硫代富瓦烯结构单元的聚硅烷制备方法,ZL200710070023.X

15. 含稠环基聚硅烷制备方法,ZL200510061319.6

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