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词条 康北笙
释义

近年来开展低维和三维功能超分子化合物和分子聚集体的研究,包括合成,结构,谱学及物理化学性质如光,电,磁等性质。 曾主持或主要参加十多项包括国家攀登、国家自然科学基金重大、重点、面上、科学院“七五”、“八五”重大、以及国家重点实验室、省自然科学基金,博士点基金等项目。 发表学术论文300余篇,参与三本国内外出版专著的编写。

个人简历

康北笙,女。浙江嘉兴人。1963年毕业于台湾大学化学系。1967年获美国芝加哥大学哲学博士学位。后在联邦德国、意大利深造。1972年回国,历任中国科学院福建物质结构研究所副研究员、结构化学研究室合成组组长、结构一室主任,福建省科协副主席,福建省第六、七届人大常委会副主任。是第五届全国政协委员。

主要学术经历

先后在美国纽约大学,布鲁克海汶国家实验室,德国卡尔斯鲁大学进行博士后研究。

1972年回国,在中国科学院福建物质结构研究所工作。1995年调入中山大学。

曾任职位

康北笙教授曾任福建省人民代表大会常务委员会副主任(六,七届)。

全国政协委员(五届),全国青年联合会五届委员。

福建省科协二,三,四届副主席,中国科协四届委员会委员。

现任职位

中国化学会理事,中国科学院福建物质结构研究所研究员。

香港中文大学客座教授,《结构化学》副主编等职。

现任国务院学位委员会学科评议组成员。

上海金属有机国家重点实验室学术委员会副主任。

广东省化学会副理事长,校学术委员会学位委员会委员。

《化学通报》、《中山大学学报(自然科学版)》编委等职。

教学成绩

曾为研究生开设《金属有机化学》,《现代物理化学专题》等专业课,为本科生介绍《固氮酶及其化学模拟》。

目前为本科生讲授《化学专业英语》。

已培养二十余名博士后,博士生,和硕士生。

多次获中国科学院自然科学奖。

科研成果获奖情况

1. 固氮酶活性中心模拟物的研究-福州模型的试探合成 中国科学院科技成果奖 一等 4 1979.

2. 同上 福建省科技成果奖 一等 4 1980.

3. 单齿硫醇配位的钼硫化合物的合成及鉴定 中国科学院科技成果奖 三等 2 1979.

4. 固氮酶活性中心模拟物合成中的笼格效应 中国科学院科技成果奖 三等 3 1983.

5. 钼铁硫(氧)链状化合物研究 中国科学院自然科学奖 三等 2 1989.

6. 过渡金属原子簇化合物的合成化学和结构化学 中国科学院自然科学奖 一等 8 1991.

7. 同上 国家自然科学奖 二等 8 1993.

8. 多核过渡金属簇(配)合物及其协同效应和簇骼转换 中国科学院自然科学奖 一等 1 1993.

9. 固相配位化学反应及原子簇合成 国家教委科技进步奖 一等 9 1995.

论文(中大第一单位)

1. Chen,Z. N.,Li,W. J.,Kang,B. S.,Hong,M. C.,Zhou,Z. Y.,Mak,T. C. W.,Lin,Zhang,Chen,X. M.,Liu,H. Q.,Heterooctanuclear cluster complex formation with phosphine-participation: Synthesis,structure,and magnetic properties of Co6Ru2(mp)10(PBu3)6,Inorg. Chem.,1997,36,(2) 208-213.

2. Chen,Z. N.,Kang,B. S.,Yu,K. B.,Tong,Y. X.,Zhang,H. X.,Su,C. Y.,Reactions of Transition metal thiolato units. Part III. The formation and characterization,structural regularity of building block complex [HNEt3][Ni(mp)(Hmp)(PBu3)] and its construction product Ni2Ru(mp)3(Hmp)(PBu3)2,Science in China B,1997,(Eng) 40 (6),634-642.

3. Kang,B. S.,Tong,Y. X.,Shi,J. C.,Liu,J. P.,Liu,G. K.,手性膦配位钯化合物的电化学性质,Electrochemical Properties of Palladium(II) Complexes with Chiral Phosphine Ligands Derived from Sugars,Acta Sci. Natur. U. Sunyatseni,(中山大学学报自然科学版) 1997,36(2),68-71.

4. Kang,B. S.,Chen,Z. N.,Tong,Y. X.,Liu,H. Q.,Gao,H. R.,Wu,B. M.,Mak,T. C. W.,Syntheses and X-ray structural characterization of phosphine cobalt (II) complexes with 2-mercaptobenzothiazole,Polyhedron,1997,16(10),1731-1737.

5. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Kang,B. S.,Extended network via axial Cu-Br linkages of zig-zag coordination chains of copper(II) ions bridged alternatively by trans-oxamidate and end-on azide groups,Chem. Lett.,1998,(3),275-27.

6. Chen,Z. N.,Li,W. J.,Kang,B. S.,Wu,B. M.,Mak,T. C. W.,Cai,Y. B.,Synthesis,crystal structure,and magnetic properties of an asymmetric,mixed valence,tetranuclear complex CoII3CoIII(mp)4(Hmp)(PMePh2)3 with 2-mercaptophenol and dimethylphenylphosphine ligands,J. Coord. Chem.,1998,44(1-2),33-45.

7. Chen,Z. N.,Li,W. J.,Kang,B. S.,Zhang,H. X.,Zhou,Z. Y.,Mak,T. C. W.,Cai,Y. B.,Hong,M. C.,Liu,H. Q.,Synthesis,structure,and magnetic properties of a cyclic heterotetranuclear complex Co3Fe(mp)4(Hmp)(PBun3)3 of 2-mercaptophenol with tri-n-butylphosphine participation,J. Chi. Chem. Soc.,(中国化学会会志) 1998,45 (3),367-373.

8. Chen,Z. N.,Zhang,H. X.,Kang,B. S.,Sun,J.,Syntheses and crystal structures of two cobalt(III) complexes Co(pym)2(PBun3)2 and Co(tpym)2(PBun3)2 with mixed phosphine and N-heterocyclic thiolato ligands,Syn. Reac. Inorg. Metal-Org. Chem.,1998,28(2),245-261.

9. Chen,Z. N.,Zhang,H. X.,Yu,B. S.,Su,C. Y.,Kang,B. S.,A trinuclear Nickel(II) complex with alternating square-planar and octahedral geometires. Synthesis,crystal structure and magnetic properties of [Ni3(oxen)2(en)][ClO4]2,Polyhedron,1998,17 (9),1535-1540.

10. Chen,Z. N.,Siu,A.,Su,C. Y.,Williams,I.,Kang,B. S.,fac-triazido(2,2¢-Biypridine-N,N')(Pyridine-N)Cobalt(III),Acta Cryst.,1998,C54,479-481.

11. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Zheng,K. C.,Cai,H.,Kang,B. S.,Extended network via hydrogen bond linkages of zig-zag coordination chains [{Cu2(trans-oxen)(m-OH)( m-H2O)}n]n+ or [Cu2(trans-oxen)( m-OCN)2]n [H2oxen = N,N'-bis(2-aminoethyl)oxamide],J. Chem. Soc. Dalton Trans.,1998,(7),1133-1136.

12. Chen,Z. N.,Zhang,H. X.,Su,C. Y.,Zhou,Z. Y.,Zheng,K. C.,Kang,B. S.,Two-dimensional sheets of rugged hexagonal grids of [Cu6(trans-oxen)3(m3-OH)2(H2O)2]n4+ with Cu(II) bridged by trans-oxen and m3-OH groups,Inorg. Chem.,1998,37 (15),3877-3880.

13. Chen,Z. N.,Kang,B. S.,Yu,K. B.,Lin,Z.,Hong,M. C.,Tong,Y. X.,Zhang,H. X.,Su,C. Y.,Reactions of Transition metal thiolato units. Part III. Building block complex [HNEt3][Ni(mp)(Hmp)(PBun3)] and the formation,characterization,and structural regularity of its construction product Ni2Ru(mp)3(Hmp)(PBun3)2,Science in China B,1998,(Chi) 28 (1),15-23.

14. Chen,Z. N.,Zhang,H. X.,Kang,B. S.,Zhou,Z. Y.,Li,W. J.,Tong,Y. X.,Su,C. Y.,A triangular cobalt-phosphine-aminothiolato complex of sulfur-capping: synthesis,structure and properties of Co3(m3-S)(abt)3(PBun3)3,Bull. Chem. Soc. Jpn.,1998,71,(8),1805-1809.

15. Chen,Z. N.,Zhang,H. X.,Yu,K. B.,Kang,B. S.,Cai,H.,Su,C. Y.,Wang,T. W.,Lu,Z. L.,3D-extended supramolecular structures via H-bonded linkages of 2D sheet-like or 1D zig-zag coordination polymers,Inorg. Chem.,1998,37(19),4775-4781.

16. Kang,B. S.,Chen,Z. N.,Su,C. Y.,Zheng,K. C.,Liu,H. Q.,Zhou,Z. Y.,Crystal and molecular structure of Co6S8(PBu3)6 and synergism in the cluster core M6E8P6 (E = S,Se,Te),Chem. J. Chi. Univ.,高等学校化学学报,1998,19,(5),760-764.

17. Kang,B. S.,Chen,Z. N.,Gao,H. R.,Zhou,Z. Y.,Wu,B. M.,Mak,T. C. W.,Lin,Z.,Syntheses and structural regularities of mixed bidentate phosphine and bidentate thiolato complexes of cobalt and nickel,Acta Chim. Sinica,1998,56(1),58-67.

18. Kang,B. S.,Chen,Z. N.,Su,C. Y.,Lin,Z.,Wen,T. B.,Reactions of Transition metal thiolato units. Part V. Formation of a binuclear Mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate),Polyhedron,1998,17(15),2497-2505.

19. Kang,B. S.,Zheng,K. C.,Zhang,H. X.,Tong,Y. X.,Wen,T. B.,Cao,R.,Synthesis and Structure of Pd(Hmp)2(PBu3)2,and the mechanism of its dimerization,Acta Phys.-Chim. Sin.,物理化学学报,1998,14(8),725-730.

20. Wen,T. B.,Kang,B. S.,Wu,D. X.,Su,C. Y.,Wang,L. G.,Liao,S.,Liu,H. Q.,Chemistry of o-mercaptophenolate: syntheses,structures,and characterization of titanium(IV) complexes,Bull. Chem. Soc. Jpn.,1998,71(10),2339-2343.

21. Lu,Z. L.,Kang,B. S.,Fun,H. K.,Razak,I. A.,Chinnakali,K.,o-Chlorobenzaledhyde nicotinoylhydrazone dihydrate,Acta Cryst. 1999,C55,89-91.

22. Kang,B. S.,Chen,Z. N.,Lin,Z.,Zhang,H. X.,Liu,H. Q.,Huang,X. Y.,Reactions of transition metal thiolato units IV. Formation of phosphine-containing cobalt or nickel complexes with i-maleonitrile-thiolate,J. Coord. Chem.,1999,46(4),409-424.

23. Kang,B. S.,Wen,T. B.,Yu,X. Y.,Zhang,H. X.,Yong,Y. X.,Su,C. Y.,Chen,Z. N.,Liu,H. Q.,Integrity and structural characteristics of the M6E8 core and the syntheses and structures of [Co6S8(PR3)6]n+ (R3 = Me2Ph,n = 1 (1); R = OMe,n = 0 (2)),J. Cluster Sci.,1999,10(3) 429-443.

24. Kang,B. S.,Wang,X. J.,Su,C. Y.,Liu,H. Q.,Wen,T. B.,Liu,Q. T.,Vanadium chemistry of o-mercaptophenol. Part IV*. Construction of heterobinuclear complexes via the synthon [V(mp)3]2- (mp = o-mercaptophenolato dianion). Syntheses and structures of (BzMe3N)2[V(mp)3] × MeCN × 1/2 MeOH and V-Co Complexes,Trans. Met. Chem.,1999,24(6),712-717.

25. Wang,X. J.,Chen,Z. F.,Kang,B. S.,Liang,H.,Liu,H. Q.,Yu,K. B.,Su,C. Y.,Chen,Z. N.,Chemistry of o-mercaptophenol (H2mp). Part III. One dimensional arrays of binuclear anions of Mo(VI) linked by Hmp-mpH via hydrogen bondings,Polyhedron,1999,18(5),647-655.

26. Wang,X. J.,Kang,B. S.,Su,C. Y.,Yu,K. B.,Zhang,H. X.,Chen,Z. N.,Function of H-bond in the conversion of a- to b-Mo8O264- ions. Formation and structure of tetra(tributylhydrogenammonium) b-octamolybdate,Polyhdron,1999,18(26),3371-3375.

27. Xiao,W.,Lu,Z. L.,Deng,L. R.,Su,C. Y.,Kang,B. S.,Synthesis and characterization of a new tripodal ligand containing ferrocenyl group,Acta Sci. Natur. Univ. Sunyatseni,中山大学学报(自然科学版),1999,38(5),127-128.

28. Xiao,W.,Lu,Z. L.,Li,R. Y.,Su,C. Y.,Kang,B. S.,S. Shanmuga,S. Raj,H.-K. Fun,1,1'-Diacetylferrocene bis(thiosemicarbazone) monohydrate,Acta Cryst.,1999,C55,1762-1764.

29. Zhang,H. X.,Chen,Z. N.,Yu,K. B.,and Kang,B. S.,Syntheses and crystal structures of two oxamidato-bridged dicopper complexes,Inorg. Chem. Commun.,1999,2 (6),223-235.

Resume(英文简历)

Name: Kang,Bei-Sheng (female),Born 1941.10.2,married,two children

EDUCATION

Sept. 1959 to June 1963 B.S. Department of Chemistry,National Taiwan University

March 1964 to Dec. 1967 Ph.D. Department of Chemistry University of Chicago

ACADEMIC PROFESSION

March 1964-Dec. 1967 Research Assistant Department of Chemistry,University of Chicago

Dec. 1967-May 1969 Post-doctorate Department of Chemistry,New York University

June 1969-Sept. 1969 Visiting Research Dep. of Chemistry,Brookhaven National Laboratory

Nov. 1969-Dec. 1970 Post-doctorate Organic Chemistry Institute,Karlsruhe University,

Oct. 1972-May 1973 Lecturer Department of Chem. and Chem. Engineering

Fuzhou University

May 1973-Feb. 1995 Professor Fujian Insitute of Research on the Structure of

Matter,Chinese Academy of Sciences

July 1992-June 1995 Honorary visiting Department of Chemistry

Professor The Chinese University of Hong Kong

Jan. 2001.1- Honorary professor Department of Biological Chemistry & Chemical

Technology,The Hong Kong Polytechnic University

March 1995-present Professor School of Chemistry and Chemical Engineering

Sun Yat-Sen University,Guangzhou,China

1999.6- Part-time professor Department of Chemistry,Henan Normal University

OTHER PROFESSION

2000- editorial board member

1987-1995 Deputy editor-in-chief (Chi. J. Strucutral Chemistry)

1988-present Vice chairman Academic Advisory Board

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry

1993.11-1997.10 member Evaluation Committee of Chemistry

Chinese Academy of Sciences

May 1997- member Evaluation Committee of Chemistry

National Advisory Council of Higher Degrees

June 1997- Vice chairman Chemical Society of Guangdong Province

RESEARCH INTEREST

Syntheses,structures and physico-chemical properties of transition metal coordination complexes,cluster compounds,and supramolecular complexes,including crystal structural,spectroscopical,electrochemical,and magnetic investigations. Structural regularities are studied,cluster formation mechanisms are interpreted,and crystal engineering processes are investigated via unit construction processes of simple structural units (building blocks)----mononuclear stable or metastable complexes or intermediates.

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