导师介绍

研究兴趣

研究成果(2011年 2010年)

导师介绍

汪志勇，1962年生于安徽合肥。现为合肥微尺度国家实验室和中国科大化学系教授，现任中国科大化学与材料学院副院长。1997年中国科学技术大学博士毕业，1997-1999期间先后在University of Tulane和 Brandeis University 从事博士后研究。2000年中科院“百人计划”引进回国，之后一直在中国科学技术大学从事有机化学的教学和科研工作。

先后主持、参加973项目、国家基金委重点项目和面上项目多项。在J. Am. Chem. Soc., Angew.chem.Int.Ed., Organic Letters, Chemical Commun, Chemistry-A Eurpean Journal 等著名国际刊物上在发表SCI 收录论文100余篇，其中 IF》3 有50余篇。先后为willey, Nova Science Publishers 出版社编写图书章节，Reusable catalyst for copper-mediated coupling reactions under heterogeous conditions（2012）， A Catalyst-Free Benzylic C–H Bond Olefination of Aza arenes for Direct Mannich-like Reactions （2011）。

研究兴趣

主要从事有机化学和生物化学的研究，包括(1)开发各种纳米催化剂，用来实现非均相有机催化反应；(2)利用氨基酸衍生物，实现有机不对称反应研究；(3)开发多种高效有机合成方法学，简化目标化合物的传统合成路线或者使合成方法绿色化； （4）设计合成多种有机小分子，用于抗艾滋病靶点药物的潜体。

研究成果

2011年

1. Enantioselective and Regioselective Friedel–Crafts Alkylation of Pyrroles with Nitroalkenes Catalyzed by a Tridentate Schiff Base–Copper Complex. F-F. Guo, D-L. Chang, G-Y. Lai, T, Zhu, S-S ,Xiong, S-J. Wang*, Z-Y. Wang* Chem. Eur. J., 2011, 17, 11127-11130.

2. Multi-functional Metal-organic frameworks based on H4mdip: crystal structure, photoluminescence, selective ion-exchange and catalysis. S-S. Xiong, S-J. Li, S-J. Wang*, Z-Y. Wang*,Cryst.Eng. Commun., 2011, 13，7236-7245.

3. Highly Efficient Amide Synthesis from Alcohols and Amines by Virtue of a Water-Soluble Gold/DNA Catalyst. Y. Wang, D-P. Zhu, L. Tang, S-J. Wang*, Z-Y. Wang*,Angew.Chem.Int.Ed., 2011, 50, 8917-8921.

4. Metal-free intramolecular oxidative decarboxylative amination of primary α-amino acids with product selectivity. Y-Z. Yan , Z-Y. Wang*,Chem. Commun., 2011, 47, 9513-9515.

5. A Catalyst-Free Benzylic C–H Bond Olefination of Aza arenes for Direct Mannich-like Reactions. Y-Z. Yan, K. Xu, Y. Fang , Z-Y. Wang* ,J. Org. Chem.,2011, 76 , 6849–6855.

6. Rational Design of Zinc–Organic Coordination Polymers Directed by N-Donor Co-ligands. S-J. Wang, S-S. Xiong, Z-Y. Wang*, J-F. Du* ,Chem. Eur. J., 2011, 17, 8630-8642.

7. Direct electrochemical imidation of aliphatic amines via anodic oxidation. L. Zhang, J-H. Su, S-J. Wang, C-F. Wan, Z-G. Zha*, Z-Y. Wang*, J-F.Du*,Chem. Commun., 2011,47, 5488-5490.

8. Four new metal–organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 ¼ dibenzothiophene-5,50-dioxide-3,7-dicarboxylic acid) ligand with guest-responsive photoluminescence. S-S. Xiong, S-J. Wang, X-J. Tang, Z-Y. Wang*, Cryst. Eng. Commun., 2011, 13, 1646-1653.

9. A metal-free decarboxylative cyclization from natural α-amino acids to construct pyridine derivatives. Q. Wang, C-F. Wan, Y. Gu, J-T. Zhang, L-F. Gao, Z-Y. Wang*,Green Chem., 2011, 13, 578-581.

10. Highly Enantioselective Henry Reaction in Water Catalyzed by a Copper-Tertiary Amine Complex and Application to the Synthesis of (S)-N-trans-Feruloyl Octopamine. -Y. Lai, F-F. Guo, Y-Q. Zheng, Y. Fang, H-G. Song, K. Xu, S-J. Wang, Z-G. Zha*, Z-Y. Wang*, Chem. Eur. J., 2011, 17, 1114-1117.

2010年

1. A DNA-templated catalyst: the preparation of metal-DNA nanohybrids and their application in organic reactions. Y. Wang,G-H. Ouyang, J-T. Zhang, Z-Y. Wang*, Chem. Commun., 2010, 46, 7912-7914.

2. An electrochemical tandem reaction: one-pot synthesis of homoallylic alcohols from alcohols in aqueous media. L. Zhang, Z-G. Zha*, Z-L. Zhang, Y-F. Li, Z-Y. Wang*, Chem. Commun., 2010, 46, 7196-7198.

3. A novel and efficient methodology for the construction of quinazolines based on supported copper oxide nanoparticles. J-T. Zhang,C-M. Yu, S-J. Wang,Z-Y. Wang*, Chem. Commun.,2010, 46, 5244-5246.

4. A simple and efficient approach to the synthesis of 2-phenylquinazolines via sp(3) C-H functionalization. J-T. Zhang,D-P. Zhu,C-M. Yu,Z-Y. Wang*, Org. Lett., 2010, 12, 2841-2843.

5. Facile synthesis of polysubstituted oxazoles via a copper-catalyzed tandem oxidative cyclization. C-F. Wan, J-T. Zhang, S-J. Wang, Z-Y. Wang*,Org. Lett., 2010, 12, 2338-2341.

6. Monodentate N-ligand-directed bifunctional transition-metal catalysis: highly enantioselective Friedel–Crafts alkylation of indoles with nitroalkenes. F-F. Guo, G-Y. Lai, S-S. Xiong, S-J. Wang, Z-Y. Wang*, Chem. Eur. J., 2010, 16, 6438-6441.

7. Simple and efficient preparation of 2,5-disubstituted oxazoles via a metal-free-catalyzed cascade cyclization. -F. Wan, L-F. Gao, Q. Wang, J-T. Zhang, Z-Y. Wang*, Org. Lett., 2010, 12, 3902–3905.

8. An efficient electrochemical method for the paired synthesis of carbonyl compounds and homoallylic alcohols in a simple home-made cell. L. Zhang, Z-G. Zha*, Z-Y. Wang*, Synlett,2010, 13,1915-1918.

9. The applications of metallic nanoparticles in coupling reactions. J-T. Zhang; C-M. Yu,S-J. Wang,Z-Y. Wang*, Prog. in Chem.,2010,22, 1482-1489.

10. Aqueous electrosynthesis of carbonyl compounds and the corresponding homoallylic alcohols in a divided cell. L. Zhang, Z-G. Zha*, Z-Y. Wang*, Tetrahedron Lett.2010, 51,1426-1429.