基本信息

内容简介

目录

基本信息

原书名：The Physics of Polymers

原出版社：Springer

作者：(德)G.斯特罗伯

丛书名：时代教育.国外高校优秀教材精选

出版社：机械工业出版社

ISBN：9787111376705

出版日期：2012 年4月

开本：16开

页码：518

版次：1-1

内容简介

《高分子物理：“结构与性能”背后的概念(英文版.原书第3版)》对高分子物理的多个领域作了生动而详细的介绍，内容涵盖链构象，高分子溶液，共混物和嵌段共聚物，半晶态聚合物，聚合物网络，聚合物流体等多种体系。作者还使用了大量的数学处理与实验结果，对提出的机理与数学模型进行示例与验证，勾勒出一幅浓墨重彩的高分子物理画卷。

《高分子物理：“结构与性能”背后的概念(英文版.原书第3版)》可作为化学化工、材料科学和物理学等专业的本科生和研究生教材，也可供有关领域的专家、学者阅读参考。

目录

《高分子物理：“结构与性能”背后的概念(英文版.原书第3版)》

出版说明

推荐序

preface（前言）

preface to the first edition/第1版前言

1constitution and architecture of chains/链的组成与构造1

2single chain conformations /单链构象15

2.1rotational isomeric states /旋转异构态15

2.2helices/螺旋19

2.3coils /线团22

2.3.1the ideal chain/理想链26

2.3.2the expanded chain/膨胀链45

2.4the persistent chain/持续链55

2.5the ising chain/ 伊辛链59

3polymer solutions /聚合物溶液69

3.1dilute and semidilute solutions/稀溶液与半稀溶液70

3.1.1osmotic pressure/渗透压71

3.2screening of excluded volume forces/排除体积力的屏蔽82

3.3polyelectrolyte solutions/聚电解质溶液89

3.3.1condensation and screening of charges /电荷的团聚与屏蔽89

3.3.2chain stretching, salt effects and interchain ordering/链伸展、盐效应与链间序95

3.3.3osmotic pressure/渗透压100

4polymer blends and block copolymers/共混物与嵌段共聚物105

4.1the flory?huggins treatment of polymer mixtures/聚合物混合物的flory?huggins处理方法106

4.1.1phase diagrams: upper and lower miscibility gap/相图：上临界与下临界混溶间隙117

4.2phase separation mechanisms/相分离机理122

4.3critical fluctuations and spinodal decomposition/临界涨落与旋节线分解129

4.3.1critical scattering/临界散射132

4.3.2decomposition kinetics/分解动力学143

4.4block copolymer phases/嵌段共聚物的相结构151

4.4.1layered structures/层状结构155

4.4.2pretransitional phenomena/前转变现象157

5the semicrystalline state/半结晶态165

5.1structure characteristics/结构特征167

5.1.1morphological elements /基本形态167

5.1.2structure parameters/结构参数173

5.2kinetics of crystallization and melting/结晶与熔融动力学181

5.3laws for the structure development/结构变化规律190

5.3.1the multistage model/多阶段模型199

5.4mechanisms of secondary crystallization/二级结晶机理205

5.4.1the insertion mode/插层模式208

5.4.2surface crystallization and melting/表面结晶与熔融212

5.5crystallization from oriented melts/取向熔体结晶216

6mechanical and dielectric response/力学与介电响应223

6.1response functions/响应函数224

6.1.1viscoelasticity/粘弹性224

6.1.2orientational polarization/取向极化228

6.1.3general relationships/通用公式229

contents6.2relaxatory modes/松弛模式236

6.2.1single?time relaxation process/单时间松弛过程237

6.2.2retardation and relaxation time spectra/推迟与松弛时间242

6.3specific relaxation processes and flow behavior/具体松弛过程与流动行为 245

6.3.1local processes/局部过程246

6.3.2glass?rubber transition and melt flow/玻璃?橡胶转变与熔体流动250

6.3.3the glass transition temperature/玻璃化转变温度269

6.3.4relaxation in partially crystalline systems/半晶体系中的松弛277

7conjugated polymers/共轭聚合物287

7.1electrooptic activity/光电活性289

7.1.1excitons and free charges/激发与自由电荷289

7.1.2electroluminescence/电发光297

7.2effects of doping/掺杂效应302

7.2.1electrical conductivity/电导率302

7.2.2magnetism and reflectivity/磁性与反射率306

8microscopic dynamics/微观运动学313

8.1the fluctuation?dissipation theorem/涨落?耗散原理313

8.2the rouse model/rouse模型317

8.2.1stress relaxation/应力松弛325

8.2.2the dielectric normal mode /介电基准模式330

8.3entanglement effects in polymer melts/聚合物熔体中的缠结效应333

8.3.1the reptation model/爬行模型338

8.4solution viscosities/溶液粘度 343

8.4.1neutral polymers: hydrodynamic interaction/中性聚合物：流体力学作用344

8.4.2polyelectrolytes: coulomb interaction/聚电解质：静电作用 352

9non?linear mechanics /非线性力学357

9.1rubber elasticity/橡胶弹性361

9.1.1the fixed junction model of ideal rubbers/理想橡胶的固定结点模型364

9.1.2the cauchy strain tensor/ cauchy应变张量371

9.1.3finger?s constitutive equation/ finger本构方程376

9.2swelling of neutral and electrolytic gels/中性与电解质凝胶的溶胀384

9.3non?newtonian melt flow/非牛顿熔体的流动390

9.3.1rheological material functions /流变材料函数391

9.3.2the lodge liquid/ lodge液体398

9.3.3the stress?optical rule/应力?光学规则404

10deformation, yielding and fracture/形变、屈服与断裂415

10.1shear deformation in semicrystalline polymers/半晶聚合物中的剪切形变418

10.1.1critical strains/临界应变418

10.1.2constituents of the drawing stress/拉伸应力的成分426

10.1.3the mechanics of neck formation/细颈形成机理429

10.1.4fibrillar state of order/纤维化有序态435

10.2crazing/银纹 444

10.3brittle fracture/脆性断裂450

10.3.1linear fracture mechanics /线性断裂力学453

10.3.2the slow mode of crack growth/裂缝生长的缓慢模式455

ascattering experiments/散射实验463

a.1fundamentals/基本概念463

a.1.1basic equations/基本方程464

a.1.2time?resolved scattering experiments/时间分解的散射实验468

a.2absolute intensities/绝对强度471

a.3low angle scattering properties/小角散射性质474

a.3.1guinier?s law/ guinier公式474

a.3.2forward scattering/前散射476

a.4special polymer systems/特种聚合物体系477

a.4.1binary mixtures and block copolymers/二元混合物与嵌段共聚物477

a.4.2two?phase layer systems/两相层状体系484

bglossary of symbols/术语与符号493

cbibliography/参考书目501

references/参考文献505

index/索引