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词条 夏永姚
释义

简介

夏永姚(Yongyao Xia) 复旦大学特聘教授,博士生导师;苏州大学兼职教授,浙江师范大学客座教授;杭州市钱江特聘专家。1965年8月出生于浙江余姚;1987年毕业于浙江师范大学化学系;1990年获吉林大学化学系电化学专业理学硕士学位;1990-1993年进入中国科学院长春应用化学研究所工作;1997年获日本佐贺大学能源-材料科学专业工学博士学位,同年留校任日本文部省教官讲师;1998年赴美国南卡罗来纳州化学工程系电化学中心做博士后研究员;1999-2001年在日本通产省大阪工业技术研究所做博士后研究员; 2001-2002年进入日立Maxell公司电池开发中心工作;2003年回复旦大学化学系工作。

研究方向

研究方向为物理化学和材料科学的交叉领域-功能材料电化学,当前主要的研究方向为(1)新型储能材料和储能技术的研究,包括液体锂离子电池、、电化学电容器、染料敏化太阳能电池、燃料电池等;(2)无机-有机纳米复合材料在储能、催化、光致发光、物质分离及生物医药等领域中的应用;3)功能材料的理论计算和模拟等研究。

成就

2003年回国至今主持包括多项863计划项目、国家自然科学基金重点基金、973计划项目子课题、上海市优秀学科带头人计划项目、国家自然科学基金面上项目,并与多家世界500强企业有合作研发项目。距今已发表SCI论文100余篇,包括Nature Chemistry, J. Am. Chem. Soc,Angew. Chem. Int. Edit.,Adv. Mater.,Adv. Fun. Mater,Chem. Mater., J. Electrochem. Soc.等,被国际学术刊物他引近2000次,单篇被他引近400次;授权和申请专利25项;参与著书3本。目前多项研究成果已经产业化。

先后获得的奖励有:2002年度日本电化学会志优秀论文奖,2005年入选教育部新世纪优秀人才计划,2009年国家自然科学基金委杰出青年基金获得者,上海市优秀学科带头人。

自述

夏教授说,他于1965年出生于大岚镇夏家岭村一个普通的农民家庭,家里共有5口人,他是老大,下面还有两个妹妹。当时,他和村里其他同龄人一样,在夏家岭小学读书,与现在大多数小学生不同的是,他们除了读书外,还要干很多农活,尽管如此,他的学习并没有拉下,1977年小学毕业后顺利考进了大岚初中。与其他农村家庭不同的是,夏永姚的父母并不希望儿子回家干农活,而是希望他继续读书,走出大山。夏永姚也很争气,1980年初中毕业后,他以优异的成绩顺利考上了梁弄中学。

考上梁弄中学是夏永姚一家最为自豪的一件事。因为当年整个四明山区,考入梁弄中学的只有3个人,夏家岭村同年一起上学的五六十名学生,由于各种原因,最终上高中的,也只有夏永姚一人。但当时条件实在是太艰苦了,特别对四明山区的孩子来说,上学不仅要步行10多公里山路,还要从自己家里带米、带菜。懂事的夏永姚没有辜负父母的期望,1983年高中毕业时,他以高出浙江省重点分数线40多分的成绩考上了浙江师范大学。正因为父母的支持,所以夏教授说父母是他“今生最为感激的人”。

大学毕业决定报考硕士研究生

说到考大学,夏教授说起一件有趣的事情,“也许是没有人指导的缘故,当时我填报的第一志愿是华东化工学院,而被录取的浙江师范大学是我填报的第五志愿。”原来,当时大学招生时,师范类和农林类的学校是提前录取的,所以尽管夏永姚当时把浙江师范大学定为第五志愿,还是被提前录取了。“大学里化学专业两个班共50几个人,就我一个人是从第五志愿录取的。” 但是,夏永姚并不后悔。因为在浙江师范大学,他打下了扎实的专业基础。大学四年,夏永姚学习一直十分努力,成绩在班上也一直领先,而且年年被评为三好学生,1987年他获得浙江师范大学理学学士学位。“当时我有两个选择,一个是找工作,另一个是考硕士研究生。”夏教授说。一般而言,对于一个经济不很富裕的家庭,他本应像大多数同学那样早早地工作,但他当时意识到自己所学的知识还不够,需要继续学习,所以最后放弃工作,报考了师资雄厚的吉林大学化学专业的硕士研究生,并被顺利录取。

工作几年后留日读博,之后回国发展

硕士毕业后,夏永姚被分配到在电池研究方面实力最为雄厚中国社会科学院长春应用化学研究所电化学研究室工作,开始电池及其材料研究。工作几年后,他有了一个去日本留学的机会。1994年2月,夏永姚告别了家人,来到日本佐贺大学理工学部攻读博士学位。当年,他是日本文部省全额奖学金资助的三名学生之一。在那里,夏永姚师从国际著名的电池研究专家芳尾真幸教授,攻读能源—材料科学专业。

在佐贺大学,夏永姚一如既往刻苦努力,3年博士学习期间,成绩相当突出,研究上也是硕果累累,共发表了近20篇论文,3年时间能发表如此多的论文,在佐贺大学是少见的,而且论文还多次被美国的SCI(《科学引文索引》)引用,其中的一篇被同行引用250多次,这说明当时夏永姚对电池的研究已经达到相当高的水平。夏永姚因此深得佐贺大学老师的厚爱,毕业那年,导师向其他院系借了一个指标,把他留下来任教,而且一开始就破格出任日本文部省教官讲师,这在日本公立大学是很少有的特例。

在佐贺大学工作期间,夏永姚曾赴美国南卡罗来纳州化学工程系电化学中心做访问学者,后返回日本,并找到了一份收入丰厚且又稳定的工作,但夏永姚总认为在国外的发展空间有限,而自己的个性又不希望被人束缚,所以最后决定回国发展。2003年1月,夏永姚辞掉工作,回到上海,被复旦大学特聘为教授、博士生导师,并担任该校学术和学位委员会委员。

走‘产—学—研’相结合的科研之路

回到复旦大学后,夏永姚积极争取科研经费,迅速筹建自己的实验室——功能材料电化学实验室。“当时,学校给我的启动资金是80万元,后来经过我多方联系,又筹集到一些资金,实验室各项工作立即开展起来。”在实验室,目前有硕士、博士12人,其他工作人员3名,还有一批本科生和企业的合作人员。

在功能材料电化学实验室外面还有一块牌子,那就是“复旦—圣比和新电源技术研发中心”,圣比和是云南个旧的一家锂电池及其材料的开发公司。2003年,也就是夏永姚刚回复旦的那年,他就是与该公司一起,成立了“复旦—圣比和新电源技术研发中心”,双方就新型高能量密度储能材料、动力锂电子电池等相关技术领域进行多形式、多方位、深层次的合作。目前,他们正在与日立(中国)有限公司以及上海奥威科技公司合作开展混合型电化学超电容器的实用化研究。

2005年,夏永姚被国家教育部选为新世纪优秀人才,为此,他觉得身上的担子更重了。事实上也是如此,迄今为止,他承担的包括国家自然科学重点和面上项目、国家863计划项目、上海市科委项目、回国留学人员基金项目、上海市引进海外高层次留学人员专项资金项目、云南省省校合作项目以及其他企业合作项目共有近10项。(刘文治)

近年发表的文章

1. Cui Wangjun, Li Feng, Liu Haijing, Wang Congxiao, Xia Yongyao. “Core-shell carbon-coated Cu6Sn5 prepared by in situ polymerization as a high-performance anode material for lithium-ion batteries“. Journal of Materials Chemistry. 19 (2009) 7202-7207. (Cover Page)

2. Liu Haijing, Cui Wangjun, Jin Linghua, Wang Congxiao, Xia Yongyao. “Preparation of three-dimensional ordered mesoporous carbon sphere arrays by a two-step templating route and their application for supercapacitors“. Journal of Materials Chemistry. 19 (2009) 3661-3667.

3. Liu Haijing, Jin Linghua, He Ping, Wang Congxiao, Xia Yongyao. “Direct synthesis of mesoporous carbon nanowires in nanotubes using MnO2 nanotubes as a template and their application in supercapacitors“. Chemical Communications. 44 (2009) 6813-6815.

4. Wang Xiaoming, Xia Yongyao. “FexC-C hybrid material as a support for Pt anode catalyst in direct formic acid fuel cell“. Electrochemistry Communications. 11 (2009) 28-30.

5. Yang Xinhui, He Ping, Xia Yongyao. “Preparation of mesocellular carbon foam and its application for lithium/oxygen battery“. Electrochemistry Communications. 11 (2009) 1127-1130.

6. Luo Jiayan, Chen Lijuan, Zhao Yujun, He Ping, Xia Yongyao. “The effect of oxygen vacancies on the structure and electrochemistry of LiTi2(PO4)3 for lithium-ion batteries: A combined experimental and theoretical study“. Journal of Power Sources. 194 (2009) 1075-1080.

7. Luo Jiayan, Xia Yongyao. “Electrochemical profile of an asymmetric supercapacitor using carbon-coated LiTi2(PO4)3 and active carbon electrodes“. Journal of Power Sources. 186 (2009) 224-227.

7. Wang Xiaoming, Xia Yongyao. “Synthesis, characterization and catalytic activity of an ultrafine Pd/C catalyst for formic acid electrooxidation“. Electrochimica Acta. 54 (2009) 7525-7530.

8. He Ping, Luo Jiayan, Yang Xinhui, Xia Yongyao. “Preparation and electrochemical profile of Li0.33MnO2 nanorods as cathode material for secondary lithium batteries“. Electrochimica Acta. 54 (2009) 7345-7349.(

9. He Ping, Luo Jiayan, He Jianxin, Xia Yongyao. “Electrochemical Profile of Oxygen-Deficient LiMn2O4-delta in Aqueous Electrolyte“. Journal of the Electrochemical Society. 156 (2009) A209-A214.

11. Wu Wen, Wang Yonggang, Li Feng, Xia Yongyao. “Electrochemical Capacitance Performance of Ordered Mesoporous Co3O4 Synthesized by Template Method“. Chinese Acta Chimica Sinica. 67 (2009) 208-212.

12. Huan-Ming Xiong*, Yang Xu, Qing-Guang Ren, and Yong-Yao Xia* , “Stable Aqueous ZnO@Polyner Core#Shell Nanoparticles with Tunable Photoluminescence and Their Application in Cell Imaging”, Journal of the American Chemical Society ,130(24),7522-7523(2008)

13. Huan-Ming Xiong*, Xiao-Yan Guan,Ling-Hua Jin, Wenn-Wen Shen,Hao-Jie Lu*,and Yong-Yao Xia* , “Surfactant-Free Synthesis of SnO 2 @PMMA and TiO 2 @PMMA Core-Shell Nanobeads Designed for Peptide/Protein Enrichment and MALDI-TOF MS Analysis”, Angew.Chem.Int.Ed, 47 4204-4207(2008)

14. Yong-Gang Wang, Wen Wu, Liang Cheng, Ping He, Cong-Xiao Wang* and Yong-Yao Xia* , “A Polyaniline Intercalated Layered Manganese Oxide Nanocomposite Prepared by Inorganic/Organic Interface Reaction and Its High Electrochemical Performance for Li Storage”, Advanced. Materials , 2166 (2008)

15. Wang-jun Cui, Cong-xiao Wang, and Yong-yao Xia *, “ Highly ordered three-dimensional macroporous FePO 4 as cathode materials for lithium-ion batteries”, Electrochemistry Communications , 10 ( 10) , 1587-1589 , ( 2008)

16. Xiao-Ming Wang, Yong yao Xia* ”electrocatalytic performance of PdCo-C catalyst for formic acid oxidation”, Electrochemistry Communications ,10, 16444-1646 (2008)

17. Hai-jing Liu, Shou-hang Bo, Wang-jun Cui, Feng Li, Cong-xiao Wang*, and Yong-yao Xia* , “Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries”, Electrochim. Acta, 53(22) , 6497-6503(2008)

18. Guo-Xian Ma, Yong-Gang Wang, Cong-Xiao Wang*, Tian-Hong Lu*, Yong-Yao Xia*, “Hemoglobin immobilized on whisker-like carbon composites and its direct electrochemistry”, Electrochimica Acta 53,4738-4753(2008)

19. Jia-Yan Luo , Jin-Long Liu, Ping He, Yong-Yao Xia* ,“ A novel LiTi 2 (PO 4 ) 3 /MnO 2 hybrid supercapacitor in lithium sulfate aqueous electrolyte ”, Electrochimica Acta , 53, ( 28) , 8128-8133(2008)

20. Feng Li, Qing-Qing Zou, and Yong-Yao Xia *, “ CoO-loaded graphitable carbon hollow spheres as anode materials for lithium-ion battery” , Journal Power Sources , 177(2), 546-552 (2008)

21. Hui-Qiao Li,Yong-Gang Wang,Cong-Xiao Wang, Yong-Yao Xia *“A competitive candidate material for aqueous supercapactiors : High suface-area graphite” Journal Power Sources , 185 ( 2008 ) 1557-1562

22. Jing-jun Zhang, Ping He,Yong-yao Xia* “Electrochemical kinetics study of Li-ion in Cu6Sn5 electrode of lithium batteries by PITT and EIS”, Journal of Electroanalytical Chemistry 624 ,161-166 (2008)

23. Ping He, Xiao Zhang, Yong-Gang Wang, Liang Cheng, and Yong-Yao Xia * , “Lithium-ion Intercalation Behavior of LiFePO 4 in Aqueous and Nonaqueous Electrolyte Solutions”, Journal of Electrochem. Society , 155(2), A144-A150 (2008)

24. Jia-Yan Luo, Huan-Ming Xiong and Yong-Yao Xia *, “LiMn 2 O 4 Nanorods, Nano-thorn Microspheres, and Hollow Nanospheres as Enhanced Cathode Materials of Lithium-ion Battery ”, Journal Physical Chemistry C , 112 (31), 12051–12057( 2008)

25. Jia-Yan Luo , Dan-Dan Zhou, Jin-Long Liu, Yongyao Xia *,“ Hybrid aqueous energy storage cells using activated carbon and lithium-ion intercalated compounds - IV. Possibility of using polymer gel electrolyte Source”, Journal of the Electrochemical Society , 155 ( 11) A789-A793 ( 2008)

26. Xiao Zhang, Cong-Xiao Wang*, Fu-You Li*, and Yong-Yao Xia *, “ A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane”, Journal of Photochemistry and Photobiology A: Chemistry, 194(1), 31-36 (2008)

27. Xiao Zhang, Jing-Jun Zhang, Yong-Yao Xia*, “Molecular design of coumarin dyes with high efficiency in dye-sensitized solar cells” , Journal of Photochemistry and Photobiology A:Chemistry , 194, 167-172 (2008)

28. Jia-Yan Luo and Yong-Yao Xia *, “ Aqueous Lithium-ion Battery LiTi 2 (PO 4 ) 3 /LiMn 2 O 4 with High Power and Energy Densities as well as Superior Cycling Stability”, Advanced Functional Materials , 17 (18), 3877-3884 (2007).

29. Yong Gang Wang, Liang Cheng, HuanMin Xiong, and Yong-Yao Xia*, “High electrocatalytic activity of oxygen reduction on an air electrode based on Mn 3 O 4 /mesoporous carbon”, Chemistry of Materials, 19, 2095 – 2101 ( 2007).

30. Jia-yan Luo, Yong-gang Wang, Huan-ming Xiong* and Yong-Yao Xia*, “Ordered Mesoporous Spinel LiMn 2 O 4 by a Soft-Chemical Process as a Cathode Material for Lithium-ion Batteries”, Chemistry of Materials, 19, 4791-4795 (2007).

31. Huan-Ming Xiong, Dong-Ping Xie, Xiao-Yan Guan, Yu-Jing Tan and Yong-Yao Xia*, “Ultrastable Blue-Emitting ZnO@Polymer Core-Shell Nanoparticles and Microspheres”, Journal of Materials Chemistry, 17 (24): 2490-2496 (2007). (Cover page).

32. Jing-jun Zhang, Xiao Zhang and Yong-Yao Xia * , “ Co doped Co x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”,Journal of Electrochem. Soc , 154(1), A7-A13 (2007).

33. Yong-gang Wang, Jia-yan Lou, Wen Wu, Cong-xiao Wang* and Yong-Yao Xia * , “ Hybrid Aqueous Energy Storage Cells Using Activated Carbon and Lithium-ion Intercalated Compounds. III. Capacity fading mechanism of Li Co 1/3 Ni 1/3 Mn 1/3 O 2 at different pH electrolyte solutions”, Journal of Electrochem. Society , 154 (3), A228-A234 (2007).

34. Liang Cheng, Xi-Li Li, Hai-Jing Liu, Huan-Ming Xiong, Ping-Wei Zhang and Yong-Yao Xia * , “ Carbon Coated Li 4 Ti 5 O 12 as a High Rate Electrode Material for Electrochemical Supercapacitors” , Journal of Electrochem. Society , 154 (7), A228-A234 (2007).

35. Huiqiao Li, Jiayan Luo, Xufeng Zhou, Chengzhong Yu* and Yong-Yao Xia*, “A new ordered mesoporous carbon with short pore length and its electrochemical performances in supercapacitor application” , Journal of Electrochem. Society , 154 (8), A731-A736 (2007).

36. Jia-Yan Luo, and Yong-Yao Xia*, “ Effect of Pore Structure on the Electrochemical Capacitive Performance of MnO 2 ”,Journal of Electrochem. Society , 154 (11), A987-A992 (2007).

37. Jiayan Luo, Liang Cheng and Yong-Yao Xia* , “ Single-Crystal LiMn 2 O 4 Hollow Nanospheres Electrode Material with Exellent Cycling Reversibility and Rate Capability”, Electrochemistry Communications, 9, 1404-1409 (2007).

38. Xiao Zhang, Jing-Jun Zhang, and Yong-Yao Xia*, “A comparative theoretical investigation of ruthenium dyes in dye-sensitized solar cells”, Journal of Photochemistry and Photobiology A: Chemistry, 185, 283-288 (2007).

39. Jia-Yan Luo, Xi-Li Li and Yong-Yao Xia * , “ Low-Temperature, Soft-Chemistry Method to Synthesize Highly Crystalline LiMn 2 O 4 Spinel Cathode Materials”, Electrochimica Acta, 52, 4525-4531 (2007)

40. Hui-qiao Li, Ying Zou, and Yong-Yao Xia*, “A study of nitroxide polyradical/activated carbon composite as the positive electrode material for electrochemical hybrid capacitor”, Electrochimica Acta, 52(5), 2153-2157 (2007) .

41. Jing-jun Zhang, Yi-min Zhang, Xiao Zhang and Yong-Yao Xia* , “ Ni x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”, Journal Power Sources , 167, 171-177 (2007).

42. Guo-Xian Ma, Tian-Hong Lu* and Yong-Yao Xia * , “ Direct electrochemistry and bioelectrocatalysis o f hemoglobin immobilized on carbon black” , Journal of Bioelectrochemistry , 71, 180-185 (2007).

43.Xin-Hui Yang, Yong-Gang Wang, Huan-Ming Xiong* and Yong-Yao Xia ,* , “Interfacial Synthesis of Porous MnO 2 and Its Application in Electrochemical Capacitor”, Electrochimica Acta, 53, 752-757 (2007).

44. Hui-Qiao Li, Rui-Li Liu, Dong-Yuan Zhao* and Yong-Yao Xia*, “Electrochemical properties of an ordered mesoporous carbon prepared by direct tri-constituent co-assembly” , Carbons , 45, 2628–2635 (2007)

45. 马国仙, 仲慧,陆天虹*,夏永姚 * ,“ 葡萄糖氧化酶在炭黑上的固定及直接电化学”,物理化学学报, 23, 1053-1058 (2007).

46. 李峰,刘海晶,王永刚,李会巧,夏永姚 * , “Zn- 空气电池中二维与三维结构碳负载 Mn 3 O 4 的催化性能比较 ”, 高等学校化学学报 , 11 , 2133-2137 (2007).

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