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词条 刘宾元
释义

刘宾元,男,1970年10出生于山东省新泰市,博士,河北工业大学教授。教育部科技发展中心科研基金和科技奖励评审专家成员,教育部学位与研究生教育评审专家成员。研究方向:专用聚烯烃材料聚合催化剂的研发及其聚烯烃材料的共混、利用二氧化碳在内的可再生资源合成高分子材料和包括耐高温聚芳醚酮和超低介电常数在内的高性能工程塑料的研发。

河北工业大学高分子化学与物理专业教授

教育情况

1992.09-1994.07泰安师范专科学校化学系

1994.09-1996.07学士曲阜师范大学化学系

1996.09-1998.10 硕士 中科院长春应化所 无机化学专业

1998.10-2001.12 博士 中科院长春应化所 高分子化学与物理专业

工作经历

2009.3- 中科院长春应用化学研究所 高级访问学者

2008.12- 河北工业大高分子科学与工程系 教授

2006.7-2007.07 韩国釜山国立大学高分子科学与工程系 访问学者

2003.03-2008.12 河北工业大高分子科学与工程系 副教授

2002.02-2003.03 韩国汉城国立大学分子科学与工程系 博士后

2001.12-2003.03 中科院长春应用化学研究所 助理研究员

教学科研工作

承担本科生“高分子材料基础”、“高分子材料发展动向”、“高分子化学与物理实验”、“高分子化学实验”和“专业外语”等课程教学工作;为研究生讲授“可控合成”, “高分子现代分析技术”(学位课),“高分子化学”(学位课)等课程教学工作。目前主持教育部科学技术研究重点项目、河北省科学技术研究与发展计划、天津市自然科学基金项目、河北省自然科学基金项目、中国石油天然气股份有限公司科学创新研究与技术开发项目各1项;主持完成国家自然科学基金、教育部留学人员科研基金项目各1项,作为第一主研人参与完成国家自然科学基金1项。在J Polym Chem Part A、Polym Degrad Stab、React Function Polym、J Appl Poly Sci、Macromol Res等期刊发表研究论文30余篇,SCI收录21篇,SCI引证30余次;会议论文数十篇;授权国家发明专利2项(第1发明人)。

承担的科研项目

1. 天津市自然科学基金“酰亚胺基聚降冰片烯低介电常数材料的制备及性能的研究”(08JCYBJC02500)(2008-2010,负责人)

2. 河北省自然科学基金“功能降冰片烯加成类聚合物的合成与性能研究”(B2008000009)(2008-2010, 负责人)

3. 河北省科技支撑计划, “聚丁烯-1制备专用Ziegler-Natta催化剂的开发”(09215110D)(2009-2011,负责人)

4. 中国石油天然气股份有限公司科学研究与技术开发项目“可调控PE分子量分布的改性钛-镁催化剂研究”(2009-2010,负责人)

5. 教育部留学人员科研基金“表面原子转移自由基聚合制备具有核壳结构的纳米复合材料的研究”(2005, 负责人)

6. 国家自然科学基金“不含氟的低介电常数纳米孔聚降冰片烯的合成及性能研究”(50403013)(2005-2007,负责人)

7. 清华大学核能与新能源技术研究院 “超微颗粒的稳定化及在有机-无机复合材料中的应用研究”(2004-2005,负责人)

8. 清华大学核能与新能源技术研究院 “氧化锆纳米复合材料的研究”(2005-2006,负责人)

9. 中国石油天然气股份有限公司科学创新研究与技术开发项目“聚丁烯-1树脂合成技术开发” (2008D5006-05-02)(2009-2010,第2)

10. 国家自然科学基金“单一主催化剂多米诺催化乙烯共聚合成LLDPE研究”(50573018)(2006-2008,第2)

11. 河北省科学技术研究与发展计划“稀土/桥联聚倍半硅氧烷的超分子构筑和发光性能”(08965110D) (2008-2010, 第2)

12. 中国石油天然气股份有限公司科学研究与技术开发项目“透明易加工LLDPE聚合中试研究” (2007-2008)

13. 教育部科学技术研究重点项目“LTL型沸石单层薄膜的定向构筑及其应用”(2008-2010,第3)

研究成果专利

1. 刘宾元, 田春英, 张莉 用于二氧化碳与环氧化合物共聚的催化剂及其制备方法,专利公开号:CN 1715307A(授权,ZL2005 1 0013808.4)

2. 刘宾元, 张莉 一种N-取代酰亚胺的制备方法 专利公开号CN1724518A (授权,ZL2005 1 0014591.9)

3. 刘宾元, 闫卫东, 章文军, 王亚琴, 曲佳燕, 张莉 合成降冰片烯与马来酸酐共聚物的方法,专利公开号 CN101045775 专利申请号200710057296.0

4. 刘宾元, 闫卫东, 李杨, 王晓亚, 曲佳燕, 张莉 含脂环基的聚N-取代降冰片烯酰亚胺及其制备方法,专利申请号CN: 200710057398.2 专利公开号:CN 101050254A

5. 刘宾元,刘宝兴,曲佳燕,张旭,杨敏 一种聚醚醚酮类聚合物及其制备方法,专利申请号200910068352.X

6. 刘宾元,赵鑫,高延浩,张莉,曲佳燕,杨敏 用于二氧化碳与环氧化合物共聚的催化剂及其制备方法和应用,专利申请号200910068351.5

7. 闫卫东,杨 敏, 刘盘阁, 刘宾元,张 旭,胡文艳,郝小宇,沈晓莉 用于制备支化聚乙烯的多米诺催化体系及其应用方法,专利公开号CN101220107 (专利申请号200710058763.1)

8. 闫卫东,杨 敏,刘宾元,郝小宇,刘盘阁,温丽芳,程 曼 以乙烯为唯一单体制备支化聚乙烯的茂金属多米诺催化体系及其应用,专利公开号CN101392036 (专利申请号200810152817.5)

9. 闫卫东,张宁宁,任合刚,张国虹,刘宾元,杨 敏,张 旭 用于合成线形低密度聚乙烯的钛/钒双金属催化剂及其制备方法和应用,专利公开号CN101220107(专利申请号200810052253.8)

代表论文

1. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene Oxide with Ln(CCl3COO)3-Based catalyst: the Role of Rare Earth Compound in the Catalytic System", J Polym Sci, Part A: Polym Chem, 2001, 39(16), 2751-2754.

2. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene oxide with Neodymium-Based Coordination Catalyst", Polymer. 2003, 44, 1803-1808.

3. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang " Thermal Degradation Kinetics of Poly (propylene carbonate) Obtained from Copolymerization of Carbon Dioxide and Propylene Oxide", J Appl Polym Sci, 2003, 90(4), 947-953.

4. Binyuan Liu, Zhixin Xue, Lu Liu, Li Zhang, Fang Liu “Modification and Characterization of Poly (ethylene-co-vinyl alcohol) by Glycosidations Reaction”,J Appl Polym Sci, 2006, 102 (1), 227-232.

5. Binyuan Liu, Chunying Tian, Li Zhang, Weidong, Yan, Wenjun Zhang “Copolymerization of Carbon Dioxide and Cyclohexene Oxide Using Zinc b-ketoiminato Complexes: Investigating the Influence of Electron Struacture of Zinc b-ketoiminato Complexes on the Catalytic Activity and Resultant Copolymer Properties”, J Polym Sci, Part A: Polym Chem, 2006,44,6243-6251.

6. Binyuan Liu, Yang Li, Li Zhang, Weidong Yan, Shuhuan Yao “Study on Thermal Degradation Kinetics of Poly (N-adamantyl-exo-nadimide) Synthesized by Addition Polymerization”, J Appl Poly Sci , 2007, 103, 3003-3009.

7. Binyuan Liu, Yang Li, IL Kim,Boo-gyo Shin, Do Yeung Yoon, Li Zhang, Rongqin Ji, Weidong Yan “Thermal Characterization and Thermal Degradation of Poly (norbornene-2, 3-dicarboxylic acid dialkyl ester)s Synthesized by Vinyl Addition Polymerization”, Polym Degrad Stabl, 2007, 92, 868-875.

8. Binyuan Liu, Yang Li, Boo-Gyo Shin, Do Yeung Yoon, IL Kim, Li Zhang, Weidong Yan “Pd (II)-Catalyzed Vinyl Addition Polymerization of Novel Functionalized Norbornene Bearing Dimethyl Carboxylate Groups", J Polym Sci, Part A: Polym Chem, 2007, 45,3391-3399.

9. Binyuan Liu, Haiqing, Li, Weidong Yan, Chang-Sik IL Kim. “Ring-opening Polymerization of e-Caprolactone and Cyclohexene Oxide Initiated by Aluminum b-Ketoamino Complexes: Steric and Electronic Effect of 3-Position Substituents of the Ligands on Polymerization”, Macromol Res, 2008, 6(5), 441- 445.

10. Binyuan Liu, Yang Li, Anu Stell Mathews, Yige Wang, Weidong Yan, Sinoj Abraham, Chang-Sik Ha, Daewon Park, IL Kim. “Synthesis of Vinyl-type Functionalized Polynorbornene with Cyclic Pendant Imide Side Groups Using Palladium-Based Catalyst for Low Dielectric Constant Materials”, React Function Polym, 2008,68, 1619-1624.

11. Min Yang, Binyuan Liu, Luhai Wang, Hegang Ren, Wenyan Hu, Lifang Wen, Weidong Yan “Novel tandem catalytic system of β-diketonate zirconium/two different cocatalysts for preparing branched polyethylene”, Catal Commun, 2009, 10, 1427-1431.

12. Boo-Gyo Shin, Tai-Yon Cho, Do Y. Yoon,Binyuan Liu “Structure and Properties of Polynorbornene Derivatives. Poly(norbornene dicarboxylic acid dialkyl ester)s and Poly(norbornene dimethyl dicarboxylate)s”, Macromol Res, 2007, 15, 185.

13. Huanrong Li, Yige Wang, Wenjun Zhang, Binyuan Liu, Gion Calzaferri "Fabrication of oriented zeolite L monolayers employing luminescent perylenediimide-bridged silsesquioxane precursor as the covalent linker", Chem Commun, 2007, 2853-2854.

14. Yige Wang, Huanrong Li, Binyuan Liu, Quanying Gan, Qinglin Dong, Gion Calzaferri, Zheng Sun, “Fabrication of oriented zeolite L monolayer via covalent molecular linkers”, J Sold Stat Chem, 2008, 181, 2469-2472.

15. Peng Liu, Huanrong Li, Yige Wang, Binyuan Liu,Wenjun Zhang, Yanji Wang, Weidong Yan, Hongjie Zhang , Ulrich Schubert.Europium complexes immobilization on titania viachemical modification of titanium alkoxide”, J Mater Chem, 2008, 18, 735 – 737.

16. Yige Wang, Huanrong Li, Wenjun Zhang, Binyuan Liu, “Luminescene properties of nanozeolite L grafted with terbium organic complex”, Mater Lett, 2008, 62(17-18), 3167-3170.

17. Yige Wang, Li Wang, Huanrong Li, Peng Liu, Dashan Qin, Binyuan Liu, Wenjun Zhang, Ruiping Deng, Hongjie Zhang, “Synthesis and luminescene properties of hybrid organic-inorganic transparent titanin thin film actived by in-situ formed lanthanide complexes”,J Sold Stat Chem, 2008, 181, 562-566.

18. Huanrong Li, Huifang Shao, Yige Wang, Dashan Qin, Binyuan Liu, Wenjun Zhang, Weidong Yan. “Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid”, Chem. Commun., 2008, 5209-5211.

19. 胡文艳, 杨敏, 赵辛, 刘宾元, 郝小宇, 闫卫东“β-二酮锆/AlEt2C/MAO催化乙烯原位共聚合成支化聚乙烯(Synthesis of Branched Polyethylene from Ethylene via in situ Copolymerization Catalyzed by β-Diketonate Zirconium/AlEt2Cl/MAO)”, 高等学校化学学报, 2008, 29(2),430-432.

20. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Functionalization of Three-Dimensionally Ordered Macroporous Cross-Linked Polystyrene by Atom-Transfer Radical Polymerization of Hydroxyethyl Methacrylate and Subsequent Derivatization” J Polym Sci, Part A: Polym Chem, 2008, 46, 7950-7959.

21. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Haiqing Li “Gaseous Infiltration Method for Preparation of Three-Dimensionally Ordered Macroporous Polyethylene”, Polymer, 2008, 49, 5446-5451.

22. 刘宾元,王晓亚,王弋戈,闫卫东,“降冰片烯酰亚胺的合成与表征”,化学试剂,2009,已录用

23. 刘宾元,高延浩,赵鑫,闫卫东“新型水杨醛衍生物的合成”,化学试剂2009,已录用

24. 毛彦科, 刘宾元,闫卫东“BP/THF引发体系引发降冰片烯与马来酸酐可见光自由基共聚合”化工新型材料,2009,已录用

25. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Preparation and Characterization of Pore Wall-Functionalized Three-dimensionally Ordered Macroporous Syndiotactic Polystyrene”, Polym Eng Sci,2009, 49, 223-228.

26. Min Yang, Wei-dong Yan, Xiao-yu Hao, Binyuan Liu, Li-fang Wen, Pan-ge Liu “Tandem Catalytic Systems: One Catalyst Combined with Two Different Activators for Preparing Branched Polyethylene with Ethylene as Single Monomer” Macromolecular, 2009, 42, 905-907.

27. Weidong Yan, Xiaoyu Hao, Min Yang, Binyuan Liu, Pange Liu “Preparation of Branched Polyethylene by A Novel Tandem Catalytic System: rac-Et(Ind)2ZrCl2/AlEt2Cl/MAO”, J Polym Sci, Part A: Polym Chem 2009, 47, 1966-1970.

28. Xu Zhang, Weidong Yan, Huifang Yang, Binyuan Liu, Pange Liu “Graft Polymerization from Pore Wall of Three-dimensionally Ordered Macroporous Cross-linked Polystyrene via Atom Transfer Radical Polymerization”, Eur Polym J, 2009, 45, 1359-1366.

29. 张宁宁,刘宾元,王卫峰,任合刚,闫卫东,Z-N催化剂内给电子体作用机理的研究进展,合成树脂与塑料,2009, 26, 73-76.

教学论文

30. 闫卫东,刘宾元,张旭,张莉,现代条件下高校教师教学基本功的内容浅析,河北工业大学学报(成人教育学院学报),2008,23(4), 19-22.

本科生参与的论文

1. Modification and Characterization of Poly (ethylene-co-vinyl alcohol) by Glycosidations Reaction,

Binyuan Liu*, Zhixin Xue, Lu Liu, Li Zhang, Fang Liu

J Appl Polym Sci, 2006, 102 (1), 227-232. SCI077QO;EI20064110167651

2.丁酰化壳聚糖的制备及结构性能表征

刘宾元,王新利,张莉,闫卫东*,李晓然,

高分子科学与工程,2007,23,130-133. EI20072710691130

3. Study on Thermal Degradation Kinetics of Poly (N-adamantyl-exo-nadimide) Synthesized by Addition Polymerization,

Binyuan Liu*, Yang Li, Li Zhang, Weidong Yan, Shuhuan Yao

J Appl Poly Sci , 2007, 103, 3003-3009. SCI129YD; EI20071010472256

4. Addition Polymerizationof Functionalized Norbornene: Effects of Pedant Imide Group on the Reactivity and Resulting Polymer Properties.

Binyuan Liu*, Xiaoya Wang, PeiWu, Weidong Yan,

International Symposium on Polymer Chemistry, PC2008, June15-19,2008,HeFei, China. P 129 (oral present)

5. Surface-confined radical chain transfer polymerization of methyl methacrylate on zirconium oxide nanoparticle

Binyuan Liu*, Ai Desheng, Li Yabin, Ji Rongqin, Liu Pange.

40 International Unin of Pure and Apllied Chemistry (IUPAC) Congress, Beijing, Preprint: 2005.

6. 新型二氧化碳与环氧化合物共聚催化剂

刘宾元,田春英, 章文军, 王振,

2005年全国高分子学术论文报告会,北京

7. 糖苷化反应修饰聚(乙烯-乙烯醇)

刘宾元, 薛志欣,刘芳,刘璐

2005年全国高分子学术论文报告会,北京

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