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词条 叶保辉
释义

人物简介

叶保辉(Ye Bao-Hui),中山大学副教授。男,1964年11月出生于海南文昌,1994年获中山大学博士学位,现任中山大学化学院无机化学与材料研究所教授,博士生导师,所长。

工作简历

1994年毕业于中山大学,获博士学位:

1994年10月至1997年10月在香港科技大学作博士后,

1997年10月到中山大学工作,并聘为副教授,

1999年7月至2001年6月获日本学术振兴会(JSPS)资助在日本九州大学(Kyushu University)作博士后特别研究员。

科研方向

讲授的主要课程:

曾讲授《无机与分析化学》、《应用无机化学》、《无机化学实验》、《配位化学》等本科生、研究生课程。指导硕士研究生、协助指导博士研究生。

主要科研方向:

功能金属配合物超分子体系的分子设计、合成和结构与性能研究,重点在超分子配合物在催化、有机合成、分离、材料化学等领域中的应用。

主持项目

1.铁(III)-铜(II)异核细胞色素C氧化酶的模拟研究(日本学术振兴会)

2.仿生水解酶的模研究(广东省自然科学基金)

3.手性配合物的识别及组装(教育部)

主要论著

近年主要论著 (全部为SCI收录)

1.Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between 13C NMR Chemical Shifts and Carboxylate Binding Modes,Bao-Hui Ye*, Xiao-Yuan Li, Ian D. Williams, Xiao-Ming Chen, Inorg. Chem. 2002, 41(24), 6426-6431

2. Interlocking of molecular rhombi into a 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4'-dicarboxylate, phen = 1,10-phenanthroline). G.-F. Liu, B.-H, Ye, Y.-H. Liu, X.-M. Chen Chem. Commun. 2002, 1442-1443.

3. The design of new molecular "light switches" for DNA, X.-H. Zuo, B.-H. Ye, H. Li, Q.-L. Zhang, H. Chao, J.-G. Liu, L.-N. Ji, X.-Y. Li, J. Biol. Inorg. Chem. 2001, 6, 143.

4. Enantiomeric ruthenium(II) complexes binding to DNA: binding modes and enantioselectivity, J.-G. Liu, B.-H. Ye, Q.-L. Zhang, X.-H. Zou, Q.-X. Zhen, X. Tian and L.-N. Ji, J. Biol. Inorg. Chem., 2000, 5(1), 119-128.

5. A novel m3-cyano-bridged hetreotrimetallic 2-D coordination polymer constructed from rectangular grids, H. Zhang, J. Cai, X.-L. Feng, B.-H. Ye, X.-Y. Li, L.-N. Ji, J. Chem. Soc. Dalton Trans. 2000, 1687.

6. Three-dimensional coordination polymers self-assembled by unusual ligand-unsupported Ag-Ag bonds. Syntheses, structures and luminescent properties of [Ag2(H2L)3]nX2n (H2L = 1,4-bis(salicyladeneamino)butane, X- = NO3- and ClO4-), M.-L. Tong, X.-M. Chen, B.-H. Ye and L.-N. Ji, Angew. Chem. Int. Ed. Engl. 1999, 38(15), 2237-2240 .

7. GIAO nuclear magnetic shielding tensors in free base porphyrin and in magnesium and zinc metalloporphyrins, P. M. Kozlowski, K. Volinski, P. Pulay, B.-H. Ye and X.-Y. Li, J. Phy. Chem. A, 1999, 103(3), 420-425.

8. DFT-SQM force field for nickel porphine: intrinsic ruffling, P. M. Kozlowski, T. S. Rush III, A. A. Jarzecki, M. Z. Zgierski, B. Chase, C. Piffat, B.-H. Ye, X.-Y. Li, P. Pulay and T. G. Spiro, J. Phy. Chem. A, 1999, 103(10), 1357-1366.

9. Syntheses, characterization and third order non-linear optical properties of the ruthenium(II) complexes containing 2-phenyl-imidazo[4,5-f][1,10]phenanthroline derivatives, H, Chao, R-H. Li, B.-H. Ye, H. Li, X.-Long Feng, J.-W. Cai, J.-Y. Zhou and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 3711-3717.

10. Mono- and binuclear ruthenium(II) complexes containing a new asymmetric ligand 3-pyrazyl-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and DNA-binding properties, X.-H. Zou, B.-H. Ye, H Li, J.-G. Liu, Y. Xiong and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1999, 1423-1428.

11. Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)2(H2O)2](ClO4)2×(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2]](ClO4)4×(4,4'-H2bpy) (M=CdII, ZnII and bpy =bipyridine), M.-L. Tong, B.-H. Ye, J.-W. Cai, X.-M. Chen and S. W. Ng, Inorg. Chem. 1998, 37, 2645-2650.

12. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via Hydrogen Bonds and p-p Stacking interactions, B.-H. Ye, X.-M. Chen, G.-Q. Xue and L.-N. Ji, J. Chem. Soc. Dalton Trans. 1998, 2827-2827.

13. Helical Silver(I)-2,4'-bipyridine Chains Organized into 2-D Networks by Metal-counterion or Metal-metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X-= NO3- or ClO4-), M.-L. Tong, X.-M. Chen, B.-H. Ye and S. W. Ng, Inorg. Chem. 1998, 37, 5278.

14. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic Hydrolases, B.-H. Ye, T. Mak, I. D. Willams and X.-Y. Li, J. Chem. Soc. Dalton Trans. 1998, 1935-1936.

15. Electronic Paramagnetic Resonance and Magnetic Properties of Model Complexes for Binuclear Active Sites in Hydrolase Enzymes, B. E. Schultz, B.-H. Ye, X.-Y. Li. S. I. Chan, Inorg. Chem. 1997, 36(12), 2617-2622.

16. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2 Bridges. Model for Dimanganese Enzymes, B.-H. Ye, T. Mak, I. D. Williams and X.-Y. Li, Chem. Commun. 1997, 1813-1814.

17. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4 Bridge from 4-Nitrophenyl Phosphate, B.-H. Ye, X.-Y. Li, F. Xue and T. C. W. Mak, Chem. Commun. 1997, 2407-2408.

18. Bis(2,2'-bipyridine)ruthenium(II) Complexes with Imidazo[4,5-f][1,10]phenanthroline or 2-phenylimidazo[4,5-f][1,10]phenanthroline, J.-Z. Wu, B.-H. Ye, L. Wang, L-N. Ji, J.-Y. Zhou, R-H. Li, Z.-Y. Zhou, J. Chem. Soc. Dalton Trans. 1997, 1395-1401.

获奖情况

1.1996年“混配配合物的生物功能、作用机制及其应用探索”1996年获广东省自然科学一等奖。(第三完成人)

2.1998年“金属酶体系的结构、机制和模拟研究”获国家教育部科技进步二等奖(基础类)。(第三完成人)

3.1998年“生物工程方法生产葡萄糖酸锌(镁、锰、内酯)新工艺的研究”获国家教育部科技进步二等奖(发明类)。

4.1998年“含羧基与多胺基的金属酶模型化合物的研究”获广东省自然科学一等奖。

5.200年“金属酶模型化合物的结构、生物功能、作用机制之间规律性”获中国高校自然科学二等奖。(第四完成人)

获专利情况:

1994年“黑曲酶发酵生产葡萄糖酸锌”获中国专利局发明专利,1996年3月27日公开,公开号:CN119213A。

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